Self-assembly of a pentanuclear {Cu5} complex resulting from the trapping of a Cu2+ ion by two {Cu2} building units
| hal.structure.identifier | Department of Chemistry | |
| dc.contributor.author | KUMAR GHOSH, Aloke | |
| hal.structure.identifier | Centre de recherches Paul Pascal [CRPP] | |
| dc.contributor.author | CLÉRAC, Rodolphe | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | MATHONIÈRE, Corine | |
| hal.structure.identifier | Department of Chemistry | |
| dc.contributor.author | RAY, Debashis | |
| dc.date.issued | 2013 | |
| dc.identifier.issn | 0277-5387 | |
| dc.description.abstractEn | The compound [Cu5(μ3-OH)2(H2bpmp)2(μ1,1-OAc)2(μ1,1,3-OAc)2(OAc)2]*2H2O (1*2H2O) (H3bpmp = 2,6-bis-[(3-hydroxy-propylimino)-methyl]-4-methyl-phenol), featuring two fused defective cubanes at a Cu2+ vertex, has been obtained via μ3-OH-bridge-driven self-assembly of two dinuclear Cu(II) phenoxido-bridged {Cu2(H2bpmp)} fragments. Antiferromagnetic interactions within the complex lead to an ST = ½ ground state for the pentanuclear arrangement. | |
| dc.language.iso | en | |
| dc.publisher | Elsevier | |
| dc.subject.en | Self-assembly | |
| dc.subject.en | Pentanuclear | |
| dc.subject.en | Trapping | |
| dc.subject.en | Schiff base | |
| dc.subject.en | Hydroxido and acetato bridges | |
| dc.subject.en | Antiferromagnetic interactions | |
| dc.title.en | Self-assembly of a pentanuclear {Cu5} complex resulting from the trapping of a Cu2+ ion by two {Cu2} building units | |
| dc.type | Article de revue | |
| dc.identifier.doi | 10.1016/j.poly.2013.02.051 | |
| dc.subject.hal | Chimie/Matériaux | |
| bordeaux.journal | Polyhedron | |
| bordeaux.page | pp. 196-200 | |
| bordeaux.volume | 54 | |
| bordeaux.peerReviewed | oui | |
| hal.identifier | hal-00808572 | |
| hal.version | 1 | |
| hal.popular | non | |
| hal.audience | Internationale | |
| hal.origin.link | https://hal.archives-ouvertes.fr//hal-00808572v1 | |
| bordeaux.COinS | ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Polyhedron&rft.date=2013&rft.volume=54&rft.spage=pp.%20196-200&rft.epage=pp.%20196-200&rft.eissn=0277-5387&rft.issn=0277-5387&rft.au=KUMAR%20GHOSH,%20Aloke&CL%C3%89RAC,%20Rodolphe&MATHONI%C3%88RE,%20Corine&RAY,%20Debashis&rft.genre=article |
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