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hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
dc.contributor.authorMUMTAZ, Muhammad
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
hal.structure.identifierTeam 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
dc.contributor.authorCLOUTET, Eric
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
hal.structure.identifierCentre de Caractérisation des Matériaux Avancés [CeCaMA]
dc.contributor.authorLABRUGÈRE, Christine
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
hal.structure.identifierTeam 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
dc.contributor.authorHADZIIOANNOU, Georges
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
dc.contributor.authorCRAMAIL, Henri
dc.date.issued2013
dc.identifier.issn1759-9954
dc.description.abstractEnWell-defined hybrid latex materials composed of a semi-conducting polymer (i.e. poly(3,4-ethylene dioxythiophene) (PEDOT)) and metal nano-objects (such as silver (Ag) or gold (Au)) were prepared by aqueous dispersion polymerization using ammonium persulfate as an oxidant and the corresponding metal salts as co-oxidants (HAuCl4 and AgNO3 respectively) in the presence of various reactive stabilizers such as aniline-modified-poly(vinyl alcohol) (PVAL-mod-An), pyrrole-modified-poly(vinyl alcohol) (PVAL-mod-Py), pyrrole-modified-poly(N-vinylpyrrolidone-co-vinyl alcohol) (PVP-co-PVAL-mod-Py), or alpha,omega-fluorene-poly(ethyleneoxide) (Flu-PEO-Flu). The effects of the nature and concentration of the reactive stabilizers as well as the addition time of the co-oxidant on the morphology of the hybrid nanoparticles thus formed are discussed. It is found that the addition time of the co-oxidant affects considerably the size and morphology of the PEDOT-metal nanocomposites.
dc.language.isoen
dc.publisherRoyal Society of Chemistry - RSC
dc.subject.enPOLY(3
dc.subject.en4-ETHYLENEDIOXYTHIOPHENE) LATEXES
dc.subject.enPHOTOELECTRON-SPECTROSCOPY
dc.subject.enREACTIVE STABILIZERS
dc.subject.enOPTICAL-PROPERTIES
dc.subject.enPOLYANILINE
dc.subject.enGOLD
dc.subject.enNANOCOMPOSITES
dc.subject.enNANOPARTICLES
dc.subject.enPARTICLES
dc.subject.enCOMPOSITES
dc.title.enSynthesis of hybrid semiconducting polymer-metal latexes
dc.typeArticle de revue
dc.identifier.doi10.1039/c2py20602a
dc.subject.halChimie/Polymères
bordeaux.journalPolymer Chemistry
bordeaux.page615-622
bordeaux.volume4
bordeaux.issue3
bordeaux.peerReviewedoui
hal.identifierhal-00817462
hal.version1
hal.popularnon
hal.audienceInternationale
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-00817462v1
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