Light-induced excited spin-state properties in 1D iron(II) chain compounds
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| hal.structure.identifier | Inorganic Chemistry II | |
| dc.contributor.author | BALDÉ, Cherif | |
| hal.structure.identifier | Inorganic Chemistry II | |
| dc.contributor.author | BAUER, Wolfgang | |
| hal.structure.identifier | Inorganic Chemistry II | |
| dc.contributor.author | KAPS, Eike | |
| hal.structure.identifier | School of Chemistry | |
| dc.contributor.author | NEVILLE, Suzanne M. | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | DESPLANCHES, Cédric | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | CHASTANET, Guillaume | |
| hal.structure.identifier | Inorganic Chemistry II | |
| dc.contributor.author | WEBER, Birgit | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | LÉTARD, Jean-François | |
| dc.date.issued | 2013 | |
| dc.identifier.issn | 1434-1948 | |
| dc.description.abstractEn | With the ultimate goal of rationally studying the factor able to affect the stability of the photoinduced high-spin state, we selected three iron(II) 1D coordination polymers with the general formula [FeLeq(Lax)]*solvent with Leq = {3,3′-[1,2-phenylenebis(iminomethylidyne)]bis(2,4-pentanedionato)(2-)-N,N′,O2,O2′}; Lax = 4,4′-bipyridine (bipy, 1), 1,2-bis(4-pyridyl)ethane (bpea, 2), and 1,3-bis(4-pyridyl)propane (bppa, 3); and solvent MeOH. This series of complexes comprises 1D chains with structures varying from linear (for bipy) over step-like (for bpea) to zigzag (for bppa). For all the materials, the thermal spin-crossover properties were measured and the stabilities of the photoinduced high-spin states were probed through determination of the T(LIESST) values associated with the light-induced excited spin-state trapping (LIESST) effect. For some of the investigated samples, the existence of steps in the relaxation of the photoinduced high-spin state was discussed. | |
| dc.language.iso | en | |
| dc.publisher | Wiley-VCH Verlag | |
| dc.subject.en | Polymers | |
| dc.subject.en | Iron | |
| dc.subject.en | Spin crossover | |
| dc.subject.en | Photomagnetism | |
| dc.title.en | Light-induced excited spin-state properties in 1D iron(II) chain compounds | |
| dc.type | Article de revue | |
| dc.identifier.doi | 10.1002/ejic.201201422 | |
| dc.subject.hal | Chimie/Matériaux | |
| bordeaux.journal | European Journal of Inorganic Chemistry | |
| bordeaux.page | 2744-2750 | |
| bordeaux.issue | 15 | |
| bordeaux.peerReviewed | oui | |
| hal.identifier | hal-00822666 | |
| hal.version | 1 | |
| hal.popular | non | |
| hal.audience | Internationale | |
| hal.origin.link | https://hal.archives-ouvertes.fr//hal-00822666v1 | |
| bordeaux.COinS | ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=European%20Journal%20of%20Inorganic%20Chemistry&rft.date=2013&rft.issue=15&rft.spage=2744-2750&rft.epage=2744-2750&rft.eissn=1434-1948&rft.issn=1434-1948&rft.au=BALD%C3%89,%20Cherif&BAUER,%20Wolfgang&KAPS,%20Eike&NEVILLE,%20Suzanne%20M.&DESPLANCHES,%20C%C3%A9dric&rft.genre=article |
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