Functionalization of silica gel with organotrialkynyltins: new method of covalent attachment of organic groups on silica gel
hal.structure.identifier | Laboratoire de chimie organique et organométallique [LCOO] | |
dc.contributor.author | BOUTET, Sandrine | |
hal.structure.identifier | Laboratoire de chimie organique et organométallique [LCOO] | |
dc.contributor.author | JOUSSEAUME, Bernard | |
hal.structure.identifier | Laboratoire de chimie organique et organométallique [LCOO] | |
dc.contributor.author | TOUPANCE, Thierry | |
hal.structure.identifier | High-Resolution NMR Centre | |
dc.contributor.author | BIESEMANS, Monique | |
hal.structure.identifier | High-Resolution NMR Centre | |
dc.contributor.author | WILLEM, Rudolph | |
hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
dc.contributor.author | LABRUGÈRE, Christine | |
hal.structure.identifier | Saint-Gobain Recherche [SGR] | |
dc.contributor.author | DELATTRE, Laurent | |
dc.date.issued | 2005 | |
dc.identifier.issn | 0897-4756 | |
dc.description.abstractEn | A new precursor molecule for chemical modification of oxide surfaces, the trialkynyl(fluoroorgano)tin(IV) (C4H9-CC)3Sn(CH2)2(CF2)7CF3, 1, was synthesized in three steps from tricyclohexyltin hydride. Compound 1 reacted with Biosepra 100 silica to give chain loadings as high as 0.28 mmol·g-1 to be compared to 0.44 mmol·g-1 reached with the trichlorosilane analogue Cl3Si(CH2)2(CF2)7CF3, 2. The modified powders have been thoroughly characterized using elemental analysis, FTIR spectroscopy, solid-state 29Si, 13C, and 29Si CP-MAS NMR, XPS, and TGA-MS. Irreversible chemisorption took place in solution at room temperature to give a fluorinated chain thin layer, likely a monolayer, via removal of three hex-1-yne molecules and formation of Sibulk-O-Sn-C linkages. The chemisorption process involves hydrolysis of the precursor in solution before reaction with the silica surface and led to surface-modified silica thermally stable up to 350 C. Trialkynylorganotins in solution might be therefore advantageously exploited to modify chemically SnO2 or TiO2 surfaces to get dye-sensitized oxide materials able to achieve light-to-electricity conversion. | |
dc.language.iso | en | |
dc.publisher | American Chemical Society | |
dc.subject.en | Organic Groups | |
dc.subject.en | Organotrialkynyltins | |
dc.subject.en | Funtionalized | |
dc.subject.en | Covalent bond | |
dc.subject.en | Silica Gel | |
dc.title.en | Functionalization of silica gel with organotrialkynyltins: new method of covalent attachment of organic groups on silica gel | |
dc.type | Article de revue | |
dc.identifier.doi | 10.1021/cm047886g | |
dc.subject.hal | Chimie/Matériaux | |
bordeaux.journal | Chemistry of Materials | |
bordeaux.page | 1803-1811 | |
bordeaux.volume | 17 | |
bordeaux.issue | 7 | |
bordeaux.peerReviewed | oui | |
hal.identifier | hal-00085749 | |
hal.version | 1 | |
hal.popular | non | |
hal.audience | Non spécifiée | |
hal.origin.link | https://hal.archives-ouvertes.fr//hal-00085749v1 | |
bordeaux.COinS | ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Chemistry%20of%20Materials&rft.date=2005&rft.volume=17&rft.issue=7&rft.spage=1803-1811&rft.epage=1803-1811&rft.eissn=0897-4756&rft.issn=0897-4756&rft.au=BOUTET,%20Sandrine&JOUSSEAUME,%20Bernard&TOUPANCE,%20Thierry&BIESEMANS,%20Monique&WILLEM,%20Rudolph&rft.genre=article |
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