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Reversible switching of the electronic ground state in a pentacoordinated Cu(ii) complex.
| hal.structure.identifier | Department of Chemistry | |
| dc.contributor.author | SASMAL, Ashok | |
| hal.structure.identifier | Department of Chemistry | |
| dc.contributor.author | SAHA, Sandeepta | |
| hal.structure.identifier | Instituto de Ciencia Molecular [ICMol] | |
| dc.contributor.author | GOMEZ-GARCIA, Carlos J. | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | DESPLANCHES, Cédric | |
| hal.structure.identifier | Department of Chemistry [Sassari] [UNISS] | |
| dc.contributor.author | GARRIBBA, Eugenio | |
| hal.structure.identifier | Depatment of Chemistry | |
| dc.contributor.author | BAUZÁ, Antonio | |
| hal.structure.identifier | Depatment of Chemistry | |
| dc.contributor.author | FRONTERA, Antonio | |
| hal.structure.identifier | Department of Chemistry | |
| dc.contributor.author | SCOTT, Reum | |
| hal.structure.identifier | Department of Chemistry | |
| dc.contributor.author | BUTCHER, Ray J. | |
| hal.structure.identifier | Department of Chemistry | |
| dc.contributor.author | MITRA, Samiran | |
| dc.date.issued | 2013 | |
| dc.identifier.issn | 1359-7345 | |
| dc.description.abstractEn | An easy reversible switching of the electronic ground state in a pentacoordinated copper(ii) complex is reported for the first time. The simple protonation of a carboxylic group in a Cu(ii) complex with a {dx(2)-y(2)}(1) electronic configuration leads to a flip of the ground electronic configuration from {dx(2)-y(2)}(1) to {dz(2)}(1) in the metal ion. | |
| dc.language.iso | en | |
| dc.publisher | Royal Society of Chemistry | |
| dc.subject.en | Reversible switching | |
| dc.subject.en | Electronic ground state | |
| dc.subject.en | Copper | |
| dc.subject.en | Inorganic compounds | |
| dc.title.en | Reversible switching of the electronic ground state in a pentacoordinated Cu(ii) complex. | |
| dc.type | Article de revue | |
| dc.identifier.doi | 10.1039/c3cc44276d | |
| dc.subject.hal | Chimie/Matériaux | |
| bordeaux.journal | Chemical Communications | |
| bordeaux.page | 7806-7808 | |
| bordeaux.volume | 49 | |
| bordeaux.issue | 71 | |
| bordeaux.peerReviewed | oui | |
| hal.identifier | hal-00861692 | |
| hal.version | 1 | |
| hal.popular | non | |
| hal.audience | Internationale | |
| hal.origin.link | https://hal.archives-ouvertes.fr//hal-00861692v1 | |
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