Rate-dependent light-induced thermal hysteresis of [Fe(PM-BiA)2(NCS)2] spin transition complex
hal.structure.identifier | Department of Solid State and Theoretical Physics | |
dc.contributor.author | ENACHESCU, Cristian | |
hal.structure.identifier | Department of Solid State and Theoretical Physics | |
dc.contributor.author | TANASA, Radu | |
hal.structure.identifier | Department of Solid State and Theoretical Physics | |
dc.contributor.author | STANCU, Alexandru | |
hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
dc.contributor.author | CHASTANET, Guillaume | |
hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
dc.contributor.author | LÉTARD, Jean-François | |
hal.structure.identifier | Laboratoire de magnétisme et d'optique de Versailles [LMOV] | |
dc.contributor.author | LINARES, Jorge | |
hal.structure.identifier | Laboratoire de magnétisme et d'optique de Versailles [LMOV] | |
dc.contributor.author | VARRET, François | |
dc.date.issued | 2006 | |
dc.identifier.issn | 0021-8979 | |
dc.description.abstractEn | The light-induced bistability under permanent irradiation (LITH: light-induced thermal hysteresis), due to the competition between light irradiation and self-accelerated relaxation, shows crucially rate-dependent hysteresis. Major and minor hysteresis loops for [Fe(PM-BiA)2(NCS)2] spin crossover compound have been measured. Using appropriate master equations, distribution data from the first-order reversal curves diagrams of the purely thermal hysteresis, and parameter values previously derived from relaxation curves, we could simulate the LITH experimental data. The tunneling contribution to the relaxation rate revealed to be a key factor for the final agreement. | |
dc.language.iso | en | |
dc.publisher | American Institute of Physics | |
dc.subject.en | Spin crossover | |
dc.subject.en | Magnetic phase boundaries | |
dc.subject.en | Optical bistability | |
dc.subject.en | multistability | |
dc.subject.en | and switching | |
dc.subject.en | including local field effects | |
dc.title.en | Rate-dependent light-induced thermal hysteresis of [Fe(PM-BiA)2(NCS)2] spin transition complex | |
dc.type | Article de revue | |
dc.identifier.doi | 10.1063/1.2167059 | |
dc.subject.hal | Chimie/Matériaux | |
bordeaux.journal | Journal of Applied Physics | |
bordeaux.page | 08J504 (3 p.) | |
bordeaux.volume | 99 | |
bordeaux.issue | 8 | |
bordeaux.peerReviewed | oui | |
hal.identifier | hal-00087018 | |
hal.version | 1 | |
hal.popular | non | |
hal.audience | Internationale | |
hal.origin.link | https://hal.archives-ouvertes.fr//hal-00087018v1 | |
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