Rational Design of a Photomagnetic Chain: Bridging Single-Molecule Magnets with a Spin-Crossover Complex
| hal.structure.identifier | Centre de recherches Paul Pascal [CRPP] | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | ABABEI, Rodica | |
| hal.structure.identifier | Centre de recherches Paul Pascal [CRPP] | |
| dc.contributor.author | PICHON, Céline | |
| hal.structure.identifier | Instituto de Ciencia de Materiales de Aragón [Saragoza, España] [ICMA-CSIC] | |
| dc.contributor.author | ROUBEAU, Olivier | |
| hal.structure.identifier | Centre de recherches Paul Pascal [CRPP] | |
| dc.contributor.author | LI, Yang-Guang | |
| hal.structure.identifier | Centre de recherches Paul Pascal [CRPP] | |
| dc.contributor.author | BRÉFUEL, Nicolas | |
| hal.structure.identifier | Centre de recherches Paul Pascal [CRPP] | |
| dc.contributor.author | BUISSON, Lionel | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | GUIONNEAU, Philippe | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | MATHONIÈRE, Corine | |
| hal.structure.identifier | Centre de recherches Paul Pascal [CRPP] | |
| dc.contributor.author | CLÉRAC, Rodolphe | |
| dc.date.created | 2013 | |
| dc.date.issued | 2013 | |
| dc.identifier.issn | 0002-7863 | |
| dc.description.abstractEn | The spin-crossover complex [Fe(LN5)(CN)2]*H2O (1, LN5 = 2,13-dimethyl-3,6,9-12,18-pentaazabicyclo[12.3.1]octadeca-1(18),2,12,14,16-pentaene), reported previously by Nelson et al. in 1986, was reinvestigated, and its structure determined by single crystal X-ray diffraction for the first time. The reaction between [MnIII(saltmen)(H2O)]+ and this photomagnetic linker yielded the trinuclear molecular complex [{Mn(saltmen)}2FeHS(LN5)(CN)2](ClO4)2* 0.5CH3OH (2) and the one-dimensional compound [{Mn(saltmen)}2FeLS(LN5)- (CN)2](ClO4)2*0.5C4H10O*0.5H2O (3) depending on the addition order of the reagents (HS: High-Spin; LS: Low-Spin). | |
| dc.language.iso | en | |
| dc.publisher | American Chemical Society | |
| dc.subject.en | Photomagnetic chain | |
| dc.subject.en | Single-molecule magnets | |
| dc.subject.en | Spin-crossover complex | |
| dc.title.en | Rational Design of a Photomagnetic Chain: Bridging Single-Molecule Magnets with a Spin-Crossover Complex | |
| dc.type | Article de revue | |
| dc.identifier.doi | 10.1021/ja407570n | |
| dc.subject.hal | Chimie/Matériaux | |
| bordeaux.journal | Journal of the American Chemical Society | |
| bordeaux.page | pp. 14840−14853 | |
| bordeaux.volume | 135 | |
| bordeaux.peerReviewed | oui | |
| hal.identifier | hal-00870774 | |
| hal.version | 1 | |
| hal.popular | non | |
| hal.audience | Internationale | |
| hal.origin.link | https://hal.archives-ouvertes.fr//hal-00870774v1 | |
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