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Continuous coflow synthesis of hybrid palladium nanocrystals as catalysts for borylation reaction.

hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorPASCU, Oana
hal.structure.identifierInstitut des Sciences Moléculaires [ISM]
dc.contributor.authorMARCIASINI, Ludovic
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorMARRE, Samuel
hal.structure.identifierInstitut des Sciences Moléculaires [ISM]
dc.contributor.authorVAULTIER, Michel
hal.structure.identifierInstitut des Sciences Moléculaires [ISM]
dc.contributor.authorPUCHEAULT, Mathieu
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorAYMONIER, Cyril
dc.date.issued2013
dc.identifier.issn2040-3364
dc.description.abstractEnThe combination of highly active Pd nanocrystal (NC) types with tailored surface properties (various ligands) - e.g. organic-inorganic hybrid NCs - as catalysts opens avenues towards new synthetic pathways, implying a faster practical alternative for adjusting and screening the reaction conditions. Pd@dppf and Pd@PCy3 NCs have been successfully prepared via a continuous supercritical fluid assisted coflow route with promising results as catalysts in borylation reaction. It has been found that the ligands not only influence the catalytic properties of the systems, but also contribute to Pd metal core characteristics (size, shape and time stability).
dc.language.isoen
dc.publisherRoyal Society of Chemistry
dc.subject.enHybrid materials
dc.subject.enNanoparticles
dc.subject.enPalladium
dc.subject.enChemical synthesis
dc.title.enContinuous coflow synthesis of hybrid palladium nanocrystals as catalysts for borylation reaction.
dc.typeArticle de revue
dc.identifier.doi10.1039/c3nr03858k
dc.subject.halChimie/Matériaux
bordeaux.journalNanoscale
bordeaux.page12425-12431
bordeaux.volume5
bordeaux.issue24
bordeaux.peerReviewedoui
hal.identifierhal-00913478
hal.version1
hal.popularnon
hal.audienceInternationale
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-00913478v1
bordeaux.COinSctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Nanoscale&rft.date=2013&rft.volume=5&rft.issue=24&rft.spage=12425-12431&rft.epage=12425-12431&rft.eissn=2040-3364&rft.issn=2040-3364&rft.au=PASCU,%20Oana&MARCIASINI,%20Ludovic&MARRE,%20Samuel&VAULTIER,%20Michel&PUCHEAULT,%20Mathieu&rft.genre=article


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