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Synthesis and crystal structure of Na3.5Cr1.5Co0.5(PO4)3 phosphate
| hal.structure.identifier | Laboratoire de Chimie des Matériaux Solides | |
| dc.contributor.author | CHAKIR, Mohamed | |
| hal.structure.identifier | Laboratoire de Chimie des Matériaux Solides | |
| dc.contributor.author | EL JAZOULI, Abdelaziz | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | CHAMINADE, Jean-Pierre | |
| dc.date.issued | 2006 | |
| dc.identifier.issn | 0885-7156 | |
| dc.description.abstractEn | A new Nasicon phosphates series [Na3+xCr2–xCox(PO4)3(0<=x<=1)] was synthesized by a coprecipitation method and structurally characterized by powder X-ray diffraction. The selected compound Na3.5Cr1.5Co0.5(PO4)3 (x=0.5) crystallizes in the R[overline 3]c space group with the following hexagonal unit-cell dimensions: ah=8.7285(3) Å, ch=21.580(2) Å, V=1423.8(1) Å3, and Z=6. This three-dimensional framework is built of PO4 tetrahedra and Cr/CoO6 octahedra sharing corners. Na atoms occupy totally M(1) sites and partially M(2) sites. | |
| dc.language.iso | en | |
| dc.publisher | Cambridge University Press (CUP) | |
| dc.subject.en | Nasicon | |
| dc.subject.en | Crystal structure | |
| dc.subject.en | Powder diffraction | |
| dc.subject.en | X-ray diffraction | |
| dc.title.en | Synthesis and crystal structure of Na3.5Cr1.5Co0.5(PO4)3 phosphate | |
| dc.type | Article de revue | |
| dc.identifier.doi | 10.1154/1.2190689 | |
| dc.subject.hal | Chimie/Matériaux | |
| bordeaux.journal | Powder Diffraction | |
| bordeaux.page | p. 210-213 | |
| bordeaux.volume | vol. 21, n° 3 | |
| bordeaux.peerReviewed | oui | |
| hal.identifier | hal-00092336 | |
| hal.version | 1 | |
| hal.popular | non | |
| hal.audience | Non spécifiée | |
| hal.origin.link | https://hal.archives-ouvertes.fr//hal-00092336v1 | |
| bordeaux.COinS | ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Powder%20Diffraction&rft.date=2006&rft.volume=vol.%2021,%20n%C2%B0%203&rft.spage=p.%20210-213&rft.epage=p.%20210-213&rft.eissn=0885-7156&rft.issn=0885-7156&rft.au=CHAKIR,%20Mohamed&EL%20JAZOULI,%20Abdelaziz&CHAMINADE,%20Jean-Pierre&rft.genre=article |
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