Effect of Niobium doping on structural, thermal, sintering and electrical properties of Bi4V1.8Cu0.2O10.7
| hal.structure.identifier | Laboratoire de Chimie des Matériaux Solides | |
| dc.contributor.author | ALGA, M. | |
| hal.structure.identifier | Laboratoire de Chimie des Matériaux Solides | |
| dc.contributor.author | AMMAR, Abdelaziz | |
| hal.structure.identifier | Laboratoire de Chimie des Matériaux Solides | |
| dc.contributor.author | TANOUTI, B. | |
| hal.structure.identifier | Laboratoire de Physique du Solide et des Couches Minces | |
| dc.contributor.author | OUTZOURHIT, A. | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | MAUVY, Fabrice | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | DECOURT, Rodolphe | |
| dc.date.issued | 2005 | |
| dc.identifier.issn | 0022-4596 | |
| dc.description.abstractEn | Doping Bi4V1.8Cu0.2O10.7 with niobium has led to the formation of the Bi4V1.8Cu0.2−xNbxO10.7+3x/2 solid solution. X-ray diffraction and thermal analysis have shown that only the compound with x=0.05 presents a tetragonal symmetry with a γ′ polymorph while the other compositions are of β polymorph. The influence of sintering temperature on the microstructure of the samples was investigated by the scanning electron microscopy (SEM). The ceramics sintered at temperatures higher than 820 °C present micro-craks. The evolution of the electrical conductivity with temperature and the degree of substitution has been investigated by impedance spectroscopy. Among all compositions studied the sample with x=0.05 presents the highest value of the conductivity. | |
| dc.language.iso | en | |
| dc.publisher | Elsevier | |
| dc.subject.en | Aurivillius phases | |
| dc.subject.en | Ionic conductors | |
| dc.subject.en | BIMEVOX materials | |
| dc.subject.en | Solid electrolyte | |
| dc.title.en | Effect of Niobium doping on structural, thermal, sintering and electrical properties of Bi4V1.8Cu0.2O10.7 | |
| dc.type | Article de revue | |
| dc.identifier.doi | 10.1016/j.jssc.2005.06.030 | |
| dc.subject.hal | Chimie/Matériaux | |
| bordeaux.journal | Journal of Solid State Chemistry | |
| bordeaux.page | p. 2873-2879 | |
| bordeaux.volume | vol. 178, n° 9 | |
| bordeaux.peerReviewed | oui | |
| hal.identifier | hal-00096665 | |
| hal.version | 1 | |
| hal.popular | non | |
| hal.audience | Non spécifiée | |
| hal.origin.link | https://hal.archives-ouvertes.fr//hal-00096665v1 | |
| bordeaux.COinS | ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Journal%20of%20Solid%20State%20Chemistry&rft.date=2005&rft.volume=vol.%20178,%20n%C2%B0%209&rft.spage=p.%202873-2879&rft.epage=p.%202873-2879&rft.eissn=0022-4596&rft.issn=0022-4596&rft.au=ALGA,%20M.&AMMAR,%20Abdelaziz&TANOUTI,%20B.&OUTZOURHIT,%20A.&MAUVY,%20Fabrice&rft.genre=article |
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