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dc.contributor.authorDHOUIB, Ikram
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorGUIONNEAU, Philippe
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorPECHEV, Stanislav
dc.contributor.authorMHIRI, Tahar
dc.contributor.authorELAOUD, Zakaria
dc.date.issued2013
dc.description.abstractEnSingle crystals of the bis‐tetrapropylammonium hexachlorodicuprate(II), [N(C3H7)4]2Cu2Cl6, were grown by slow evaporation solution technique at room temperature. The compound was characterized by Raman, IR and single crystal X‐ray diffraction studies. Crystal data for C12H28Cl3CuN (M = 356.24 g/mol): triclinic, space group P‐1 (no. 2), a = 9.3851(2) Å, b = 9.3844(2) Å, c = 11.8837(3) Å, α = 106.3330(11)°, β = 100.0280(12)°, γ = 113.2830(12)°, V = 872.95(3) Å3, Z = 2, T = 293(2) K, μ(MoKα) = 1.693 mm‐1, Dcalc = 1.355 g/mm3, 8056 reflections measured (6.64 ≤ 2Θ ≤ 62.02), 5526 unique (Rint = 0.0303) which were used in all calculations. The final R1 was 0.0427 (>2σ(I)) and wR2 was 0.1312 (all data). The atomic arrangement can be described by alternating organic and inorganic layers parallel to the (101) plan, made up of tetrapropylammonium groups and Cu2Cl6 dimers, respectively. In crystal structure, the inorganic layers, built up by Cu2Cl6 dimers, are connected to the organic ones through hydrogen bonding C‐H...Cl and Van der Waals interaction in order to build cation‐anion‐cation cohesion. These interactions cause to the formation of a three‐dimensional supramolecular architecture.
dc.language.isoen
dc.typeArticle de revue
dc.identifier.doi10.5155/eurjchem.4.2.117-120.738
dc.subject.halChimie/Matériaux
bordeaux.journalEuropean journal of chemistry
bordeaux.page117‐120
bordeaux.volume4
bordeaux.issue2
bordeaux.peerReviewedoui
hal.identifierhal-00986968
hal.version1
hal.popularnon
hal.audienceInternationale
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-00986968v1
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