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Diketo-Pyrrolo Pyrrole-Based Acceptor-Acceptor Copolymers with Deep HOMO and LUMO Levels Absorbing in the Near Infrared
| dc.rights.license | open | en_US |
| dc.contributor.author | KHELIFI, Wissem | |
| dc.contributor.author | AWADA, Hussein | |
| dc.contributor.author | BLANC, Sylvie | |
| hal.structure.identifier | Laboratoire de l'intégration, du matériau au système [IMS] | |
| dc.contributor.author | ROCHE, Gilles | |
| hal.structure.identifier | Laboratoire de l'intégration, du matériau au système [IMS] | |
| dc.contributor.author | HIRSCH, Lionel
IDREF: 111272459 | |
| hal.structure.identifier | Institut des Sciences Moléculaires [ISM] | |
| dc.contributor.author | OBOHO, Bassey | |
| hal.structure.identifier | Institut des Sciences Moléculaires [ISM] | |
| dc.contributor.author | CASTET, Frédéric | |
| dc.contributor.author | BOUSQUET, Antoine | |
| dc.contributor.author | LARTIGAU-DAGRON, Christine | |
| dc.date.accessioned | 2022-07-13T12:51:24Z | |
| dc.date.available | 2022-07-13T12:51:24Z | |
| dc.date.issued | 2022 | |
| dc.identifier.issn | 2076-3417 | en_US |
| dc.identifier.uri | https://oskar-bordeaux.fr/handle/20.500.12278/140482 | |
| dc.description.abstractEn | A series of acceptor-acceptor (A-A') alternated copolymers based on dithienodiketopyrrolo pyrrole were synthesized by copolymerizing it with itself and other different electron-poor monomers. The experimental and computed optoelectronic properties of four DPP-based copolymers, P(DPP-DPP) (with linear and branched chains), copolymer with diazapentalene P(DPP-DAP) and also with dioxothienopyrrolebenzodifurandione P(DPP-BTPBF), as well as thermal characterizations were described. UV-visible spectrophotometry and cyclic voltammetry were used to estimate the optical and electrochemical bandgaps, and were found as very small: 1.3, 1.0, and 0.9 eV for P(DPP-DPP), P(DPP-DAP), and P(DPP-BTPBF), respectively. The BTPBF unit allowed a strong reduction of the bandgap, leading to a broad absorption in the visible and near infra-red regions from 650 to 1450 nm. These results were compared to analogous donor-acceptor (D-A) copolymers previously reported, in which DPP is replaced by DTS, P(DTS-DPP), P(DTS-DAP), and P(DTS-BTPBF). The same trend was observed. By comparing A-A' to D-A' copolymers analogues, it was shown that the bandgap remained the same while both HOMO and LUMO levels were lowered by roughly 0.2 eV. | |
| dc.description.sponsorship | Technologie alternative pour les photodétecteurs infrarouge - ANR-15-CE24-0024 | en_US |
| dc.description.sponsorship | E2S - ANR-16-IDEX-0002 | en_US |
| dc.language.iso | EN | en_US |
| dc.rights | Attribution 3.0 United States | * |
| dc.rights.uri | http://creativecommons.org/licenses/by/3.0/us/ | * |
| dc.subject.en | copolymer | |
| dc.subject.en | near infra-red | |
| dc.subject.en | low bandgap | |
| dc.title.en | Diketo-Pyrrolo Pyrrole-Based Acceptor-Acceptor Copolymers with Deep HOMO and LUMO Levels Absorbing in the Near Infrared | |
| dc.type | Article de revue | en_US |
| dc.identifier.doi | 10.3390/app12094494 | en_US |
| dc.subject.hal | Chimie/Matériaux | en_US |
| dc.subject.hal | Chimie/Polymères | en_US |
| dc.subject.hal | Chimie/Chimie théorique et/ou physique | en_US |
| dc.subject.hal | Chimie/Chimie analytique | en_US |
| bordeaux.journal | Applied Sciences | en_US |
| bordeaux.page | 4494 | en_US |
| bordeaux.hal.laboratories | Laboratoire d’Intégration du Matériau au Système (IMS) - UMR 5218 | en_US |
| bordeaux.issue | 12 | en_US |
| bordeaux.institution | Université de Bordeaux | en_US |
| bordeaux.institution | Bordeaux INP | en_US |
| bordeaux.institution | CNRS | en_US |
| bordeaux.peerReviewed | oui | en_US |
| bordeaux.inpress | non | en_US |
| bordeaux.import.source | hal | |
| hal.identifier | hal-03654909 | |
| hal.version | 1 | |
| hal.export | false | |
| workflow.import.source | hal | |
| dc.rights.cc | Pas de Licence CC | en_US |
| bordeaux.COinS | ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Applied%20Sciences&rft.date=2022&rft.issue=12&rft.spage=4494&rft.epage=4494&rft.eissn=2076-3417&rft.issn=2076-3417&rft.au=KHELIFI,%20Wissem&AWADA,%20Hussein&BLANC,%20Sylvie&ROCHE,%20Gilles&HIRSCH,%20Lionel&rft.genre=article |
