Synthesis and Multibromination of Nanosized Helical Aromatic Amide Foldamers via Segment-Doubling Condensation
| dc.contributor.author | LI, Xuesong | |
| dc.contributor.author | QI, Ting | |
| dc.contributor.author | SRINIVAS, Kolupula | |
| dc.contributor.author | MASSIP, Stephane | |
| dc.contributor.author | MAURIZOT, Victor | |
| dc.contributor.author | HUC, Ivan | |
| dc.date.accessioned | 2020-09-03T07:56:12Z | |
| dc.date.available | 2020-09-03T07:56:12Z | |
| dc.date.issued | 2016 | |
| dc.identifier.issn | 1523-7060 | |
| dc.identifier.uri | https://oskar-bordeaux.fr/handle/20.500.12278/10846 | |
| dc.description.abstractEn | The synthesis of very long helical aromatic amide foldamers was thought to be limited by steric hindrance associated with stable folded conformations. This difficulty may be overcome by using pure reagents, relatively high concentrations, and long reaction times. Bromine substituents and careful identification and elimination of anhydride byproducts both greatly improve chromatographic purification, giving access to pure products amenable to a segment-doubling synthesis of sequences composed of up to 96 monomers. An efficient one-pot multibromination of helical oligomers is also reported. | |
| dc.language.iso | en | |
| dc.title.en | Synthesis and Multibromination of Nanosized Helical Aromatic Amide Foldamers via Segment-Doubling Condensation | |
| dc.type | Article de revue | |
| dc.identifier.doi | 10.1021/acs.orglett.6b00165 | |
| dc.subject.hal | Chimie/Matériaux | |
| bordeaux.journal | Organic Letters | |
| bordeaux.page | 1044-1047 | |
| bordeaux.volume | 18 | |
| bordeaux.hal.laboratories | Institut de Chimie & de Biologie des Membranes & des Nano-objets (CBMN) - UMR 5248 | * |
| bordeaux.hal.laboratories | Institut de Chimie & de Biologie des Membranes & des Nano-objets (CBMN, UMR 5248) | |
| bordeaux.issue | 5 | |
| bordeaux.institution | Université de Bordeaux | |
| bordeaux.institution | Bordeaux INP | |
| bordeaux.COinS | ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Organic%20Letters&rft.date=2016&rft.volume=18&rft.issue=5&rft.spage=1044-1047&rft.epage=1044-1047&rft.eissn=1523-7060&rft.issn=1523-7060&rft.au=LI,%20Xuesong&QI,%20Ting&SRINIVAS,%20Kolupula&MASSIP,%20Stephane&MAURIZOT,%20Victor&rft.genre=article |
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