Bio-Based Polyricinoleate and Polyhydroxystearate: Properties and Evaluation as Viscosity Modifiers for Lubricants
| dc.rights.license | open | en_US |
| hal.structure.identifier | Laboratoire de Chimie des Polymères Organiques [LCPO] | |
| hal.structure.identifier | Team 2 LCPO : Biopolymers & Bio-sourced Polymers | |
| dc.contributor.author | MÉHEUST, Hélène | |
| hal.structure.identifier | Laboratoire de Chimie des Polymères Organiques [LCPO] | |
| hal.structure.identifier | Team 3 LCPO : Polymer Self-Assembly & Life Sciences | |
| dc.contributor.author | LE MEINS, Jean-Francois | |
| hal.structure.identifier | Laboratoire de Chimie des Polymères Organiques [LCPO] | |
| hal.structure.identifier | Team 2 LCPO : Biopolymers & Bio-sourced Polymers | |
| dc.contributor.author | GRAU, Etienne
IDREF: 187909261 | |
| hal.structure.identifier | Laboratoire de Chimie des Polymères Organiques [LCPO] | |
| hal.structure.identifier | Team 2 LCPO : Biopolymers & Bio-sourced Polymers | |
| dc.contributor.author | CRAMAIL, Henri | |
| dc.date.accessioned | 2021-01-13T15:48:44Z | |
| dc.date.available | 2021-01-13T15:48:44Z | |
| dc.date.issued | 2021-01-04 | |
| dc.identifier.uri | oai:crossref.org:10.1021/acsapm.0c01153 | |
| dc.identifier.uri | https://oskar-bordeaux.fr/handle/20.500.12278/25769 | |
| dc.description.abstractEn | This paper aims to design bio-based polyester as a viscosity modifier for lubricant properties. Bio-based polyricinoleate (PRic) and its saturated homologous polyhydroxystearate (PHS) have been synthesized from fatty acid methyl esters. The polycondensation performed in bulk in a one-step reaction without any purification leads to two series of polyesters within a large range of molecular weights, with Mw between 3 and 130 kg·mol–1. Their thermal properties were investigated. Good thermal stability was observed with degradation temperatures above 300 °C. As expected, PRic appeared to be amorphous with a particularly low glass-transition temperature, while PHS is semicrystalline. A rheological study determined that polyricinoleate entangled when its molecular weight was above 25 kg·mol–1. These two bio-based and biodegradable polymers were then evaluated as viscosity modifiers in both organic and mineral oils. PHS with high molecular weights appeared to be an excellent thickener as well as a good viscosity index improver with a viscosity index (VI) increase above +50 in organic lubricant oil and +64 in mineral oil. | |
| dc.language.iso | EN | en_US |
| dc.rights | Attribution-NonCommercial-NoDerivs 3.0 United States | * |
| dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/3.0/us/ | * |
| dc.source | crossref | |
| dc.subject.en | polyricinoleate | |
| dc.subject.en | polyhydroxystearate | |
| dc.subject.en | lubricant | |
| dc.subject.en | viscosity modifiers | |
| dc.subject.en | thickeners | |
| dc.subject.en | viscosity index | |
| dc.title.en | Bio-Based Polyricinoleate and Polyhydroxystearate: Properties and Evaluation as Viscosity Modifiers for Lubricants | |
| dc.type | Article de revue | en_US |
| dc.identifier.doi | 10.1021/acsapm.0c01153 | en_US |
| dc.subject.hal | Chimie/Polymères | en_US |
| bordeaux.journal | ACS Applied Polymer Materials | |
| bordeaux.volume | 3 | en_US |
| bordeaux.hal.laboratories | Laboratoire de Chimie des Polymères Organiques (LCPO) - UMR 5629 | en_US |
| bordeaux.institution | Bordeaux INP | en_US |
| bordeaux.institution | Université de Bordeaux | en_US |
| bordeaux.peerReviewed | oui | en_US |
| bordeaux.inpress | non | en_US |
| bordeaux.import.source | dissemin | |
| hal.identifier | hal-03109425 | |
| hal.version | 1 | |
| hal.date.transferred | 2021-01-13T16:27:31Z | |
| hal.export | true | |
| workflow.import.source | dissemin | |
| bordeaux.COinS | ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=ACS%20Applied%20Polymer%20Materials&rft.date=2021-01-04&rft.volume=3&rft.au=M%C3%89HEUST,%20H%C3%A9l%C3%A8ne&LE%20MEINS,%20Jean-Francois&GRAU,%20Etienne&CRAMAIL,%20Henri&rft.genre=article |
