Controlled polymerization of glycidyl methyl ether initiated by onium salt/triisobutylaluminum and investigation of the polymer LCST
| dc.rights.license | open | |
| hal.structure.identifier | Laboratoire de Chimie des polymères organiques [LCPO] | |
| dc.contributor.author | LABBÉ, Amélie | |
| hal.structure.identifier | Laboratoire de Chimie des polymères organiques [LCPO] | |
| hal.structure.identifier | Team 1 LCPO : Polymerization Catalyses & Engineering | |
| dc.contributor.author | CARLOTTI, Stéphane | |
| hal.structure.identifier | Laboratoire de Chimie des polymères organiques [LCPO] | |
| dc.contributor.author | DEFFIEUX, Alain | |
| hal.structure.identifier | Polymeric and Organic Department, TIT Tokyo | |
| dc.contributor.author | HIRAO, Akira | |
| dc.date.accessioned | 2020 | |
| dc.date.available | 2020 | |
| dc.date.issued | 2007 | |
| dc.identifier.issn | 1022-1360 | |
| dc.identifier.uri | https://oskar-bordeaux.fr/handle/20.500.12278/20819 | |
| dc.description.abstractEn | New initiating systems developed for monomer activated anionic polymerization of propylene oxide, i.e. onium salt/triisobutylaluminum, were applied to the polymerization of glycidyl methyl ether. At low to medium temperature they yield fast polymerization and allow the synthesis of poly(glycidyl methyl ether) with high molar masses in a controlled way. Poly(glycidyl methyl ether) exhibits a critical solubility temperature (LCST) in water which is influenced by the polymer molar masses. Surprisingly poly(glycidyl methyl ether)s show also some tendency to crystallize in water at low temperature, which perturb their solubility characteristics and behaviour in water. | |
| dc.language.iso | en | |
| dc.publisher | Wiley-VCH Verlag | |
| dc.subject.en | water | |
| dc.subject.en | solubility | |
| dc.subject.en | polymerisation | |
| dc.subject.en | polymers | |
| dc.title.en | Controlled polymerization of glycidyl methyl ether initiated by onium salt/triisobutylaluminum and investigation of the polymer LCST | |
| dc.type | Article de revue | |
| dc.identifier.doi | 10.1002/masy.200750409 | |
| dc.subject.hal | Chimie/Polymères | |
| bordeaux.journal | Macromolecular Symposia | |
| bordeaux.page | 392-397 | |
| bordeaux.volume | 249 | |
| bordeaux.hal.laboratories | Laboratoire de Chimie des Polymères Organiques (LCPO) - UMR 5629 | * |
| bordeaux.institution | Bordeaux INP | |
| bordeaux.institution | Université de Bordeaux | |
| bordeaux.peerReviewed | oui | |
| hal.identifier | hal-00279954 | |
| hal.version | 1 | |
| hal.origin.link | https://hal.archives-ouvertes.fr//hal-00279954v1 | |
| bordeaux.COinS | ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Macromolecular%20Symposia&rft.date=2007&rft.volume=249&rft.spage=392-397&rft.epage=392-397&rft.eissn=1022-1360&rft.issn=1022-1360&rft.au=LABB%C3%89,%20Am%C3%A9lie&CARLOTTI,%20St%C3%A9phane&DEFFIEUX,%20Alain&HIRAO,%20Akira&rft.genre=article |
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