Dendrimer-like polymers: a new class of structurally precise dendrimers with macromolecular generations
dc.rights.license | open | |
hal.structure.identifier | Laboratoire de Chimie des polymères organiques [LCPO] | |
hal.structure.identifier | Team 1 LCPO : Polymerization Catalyses & Engineering | |
dc.contributor.author | TATON, Daniel | |
hal.structure.identifier | Laboratoire de Chimie des polymères organiques [LCPO] | |
dc.contributor.author | FENG, Xiaoshuang | |
hal.structure.identifier | Laboratoire de Chimie des polymères organiques [LCPO] | |
dc.contributor.author | GNANOU, Yves | |
dc.date.accessioned | 2020 | |
dc.date.available | 2020 | |
dc.date.issued | 2007 | |
dc.identifier.issn | 1144-0546 | |
dc.identifier.uri | https://oskar-bordeaux.fr/handle/20.500.12278/20811 | |
dc.description.abstractEn | A new class of highly branched polymers referred to as dendrimer-like polymers has been developed in the last decade, the first synthetic example dating back to 1995. Dendrimer-like polymers exhibit molecular features similar to those of regular dendrimers, such as the presence of a central core, a precise number of branching points and terminal functions, but comprise of generations of macromolecular size between their branching junctions. In this highlight article synthetic strategies to dendrimer-like polymers are reviewed as well as some of their characteristic properties. A special emphasis is placed on synthetic methodologies designed in our group to generate dendrimer-like homopolymers and block copolymers by iterative divergent approaches based on anionic ring-opening polymerization of ethylene oxide and atom transfer radical polymerization. Are also thoroughly described the methods used for selectively branching polymeric chain-ends and introducing omega-geminal functionalities from which further macromolecular generations could be grown. | |
dc.language.iso | en | |
dc.publisher | Royal Society of Chemistry | |
dc.subject.en | Poly(acrylic acid) | |
dc.subject.en | Polycaprolactone | |
dc.subject.en | Poly(ethylene oxide) | |
dc.subject.en | Polystyrene | |
dc.subject.en | Atom Transfer Radical Polymerization | |
dc.subject.en | Anionic Ring Opening Polymerization | |
dc.subject.en | Stars | |
dc.subject.en | Dendrimer-like polymers | |
dc.subject.en | Branching Agents | |
dc.subject.en | Poly(methyl methacrylate) | |
dc.title.en | Dendrimer-like polymers: a new class of structurally precise dendrimers with macromolecular generations | |
dc.type | Article de revue | |
dc.identifier.doi | 10.1039/b618544b | |
dc.subject.hal | Chimie/Polymères | |
bordeaux.journal | New Journal of Chemistry | |
bordeaux.page | 1097-1110 | |
bordeaux.volume | 31 | |
bordeaux.hal.laboratories | Laboratoire de Chimie des Polymères Organiques (LCPO) - UMR 5629 | * |
bordeaux.issue | 7 | |
bordeaux.institution | Bordeaux INP | |
bordeaux.institution | Université de Bordeaux | |
bordeaux.peerReviewed | oui | |
hal.identifier | hal-00282541 | |
hal.version | 1 | |
hal.origin.link | https://hal.archives-ouvertes.fr//hal-00282541v1 | |
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