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hal.structure.identifierLaboratoire de Chimie des polymères organiques [LCPO]
hal.structure.identifierTeam 1 LCPO : Polymerization Catalyses & Engineering
dc.contributor.authorTATON, Daniel
hal.structure.identifierLaboratoire de Chimie des polymères organiques [LCPO]
dc.contributor.authorFENG, Xiaoshuang
hal.structure.identifierLaboratoire de Chimie des polymères organiques [LCPO]
dc.contributor.authorGNANOU, Yves
dc.date.accessioned2020
dc.date.available2020
dc.date.issued2007
dc.identifier.issn1144-0546
dc.identifier.urihttps://oskar-bordeaux.fr/handle/20.500.12278/20811
dc.description.abstractEnA new class of highly branched polymers referred to as dendrimer-like polymers has been developed in the last decade, the first synthetic example dating back to 1995. Dendrimer-like polymers exhibit molecular features similar to those of regular dendrimers, such as the presence of a central core, a precise number of branching points and terminal functions, but comprise of generations of macromolecular size between their branching junctions. In this highlight article synthetic strategies to dendrimer-like polymers are reviewed as well as some of their characteristic properties. A special emphasis is placed on synthetic methodologies designed in our group to generate dendrimer-like homopolymers and block copolymers by iterative divergent approaches based on anionic ring-opening polymerization of ethylene oxide and atom transfer radical polymerization. Are also thoroughly described the methods used for selectively branching polymeric chain-ends and introducing omega-geminal functionalities from which further macromolecular generations could be grown.
dc.language.isoen
dc.publisherRoyal Society of Chemistry
dc.subject.enPoly(acrylic acid)
dc.subject.enPolycaprolactone
dc.subject.enPoly(ethylene oxide)
dc.subject.enPolystyrene
dc.subject.enAtom Transfer Radical Polymerization
dc.subject.enAnionic Ring Opening Polymerization
dc.subject.enStars
dc.subject.enDendrimer-like polymers
dc.subject.enBranching Agents
dc.subject.enPoly(methyl methacrylate)
dc.title.enDendrimer-like polymers: a new class of structurally precise dendrimers with macromolecular generations
dc.typeArticle de revue
dc.identifier.doi10.1039/b618544b
dc.subject.halChimie/Polymères
bordeaux.journalNew Journal of Chemistry
bordeaux.page1097-1110
bordeaux.volume31
bordeaux.hal.laboratoriesLaboratoire de Chimie des Polymères Organiques (LCPO) - UMR 5629*
bordeaux.issue7
bordeaux.institutionBordeaux INP
bordeaux.institutionUniversité de Bordeaux
bordeaux.peerReviewedoui
hal.identifierhal-00282541
hal.version1
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-00282541v1
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