Cross olefin metathesis for the selective functionalization, ferrocenylation, and solubilisation in water of olefin-terminated dendrimers, polymers, and gold nanoparticles and for a divergent dendrimer construction
| dc.rights.license | open | |
| hal.structure.identifier | Institut des Sciences Moléculaires [ISM] | |
| dc.contributor.author | ORNELAS, Catia | |
| hal.structure.identifier | Institut des Sciences Moléculaires [ISM] | |
| dc.contributor.author | MÉRY, Denise | |
| hal.structure.identifier | Laboratoire de Chimie des polymères organiques [LCPO] | |
| hal.structure.identifier | Team 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies | |
| dc.contributor.author | CLOUTET, Eric
IDREF: 151048681 | |
| hal.structure.identifier | Institut des Sciences Moléculaires [ISM] | |
| dc.contributor.author | ARANZAES, Jaime Ruiz | |
| hal.structure.identifier | Institut des Sciences Moléculaires [ISM] | |
| dc.contributor.author | ASTRUC, Didier | |
| dc.date.accessioned | 2020 | |
| dc.date.available | 2020 | |
| dc.date.issued | 2008 | |
| dc.identifier.issn | 0002-7863 | |
| dc.identifier.uri | https://oskar-bordeaux.fr/handle/20.500.12278/20800 | |
| dc.description.abstractEn | Olefin cross metathesis was used to efficiently functionalize, polyolefin dendrimers, polymers, and gold nanoparticles using the second-generation Grubbs catalyst. In these structures, the tethers were lengthened to prevent the facile cross metathesis that otherwise predominates in polyolefin dendrimers having short tethers. This synthetic strategy allows the one-step access to polyacid, polyester, and polyferrocenyl structures from polyolefins. Cross metathesis is also used to efficiently achieve an iterative divergent dendritic construction. All the cross metathesis reactions were monitored by H-1 NMR showing the chemio-, regio-, and stereoselectivity. MALDI-TOF mass spectrometry was a very useful technique to confirm the efficiency of this synthetic strategy | |
| dc.language.iso | en | |
| dc.publisher | American Chemical Society | |
| dc.subject.en | divergent | |
| dc.subject.en | gold nanoparticles | |
| dc.subject.en | dendrimer | |
| dc.subject.en | olefin cross metathesis | |
| dc.title.en | Cross olefin metathesis for the selective functionalization, ferrocenylation, and solubilisation in water of olefin-terminated dendrimers, polymers, and gold nanoparticles and for a divergent dendrimer construction | |
| dc.type | Article de revue | |
| dc.identifier.doi | 10.1021/ja077392v | |
| dc.subject.hal | Chimie/Polymères | |
| bordeaux.journal | Journal of the American Chemical Society | |
| bordeaux.page | 1495-1506 | |
| bordeaux.volume | 130 | |
| bordeaux.hal.laboratories | Laboratoire de Chimie des Polymères Organiques (LCPO) - UMR 5629 | * |
| bordeaux.issue | 4 | |
| bordeaux.institution | Bordeaux INP | |
| bordeaux.institution | Université de Bordeaux | |
| bordeaux.peerReviewed | oui | |
| hal.identifier | hal-00315538 | |
| hal.version | 1 | |
| hal.origin.link | https://hal.archives-ouvertes.fr//hal-00315538v1 | |
| bordeaux.COinS | ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Journal%20of%20the%20American%20Chemical%20Society&rft.date=2008&rft.volume=130&rft.issue=4&rft.spage=1495-1506&rft.epage=1495-1506&rft.eissn=0002-7863&rft.issn=0002-7863&rft.au=ORNELAS,%20Catia&M%C3%89RY,%20Denise&CLOUTET,%20Eric&ARANZAES,%20Jaime%20Ruiz&ASTRUC,%20Didier&rft.genre=article |
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