Polymer micelles as supports for the production of millimetric polyethylene beads
| dc.rights.license | open | |
| hal.structure.identifier | Laboratoire de Chimie des polymères organiques [LCPO] | |
| dc.contributor.author | BOUILHAC, Cécile | |
| hal.structure.identifier | Laboratoire de Chimie des polymères organiques [LCPO] | |
| hal.structure.identifier | Team 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies | |
| dc.contributor.author | CLOUTET, Eric
IDREF: 151048681 | |
| hal.structure.identifier | Laboratoire de Chimie des polymères organiques [LCPO] | |
| hal.structure.identifier | Team 1 LCPO : Polymerization Catalyses & Engineering | |
| dc.contributor.author | TATON, Daniel | |
| hal.structure.identifier | Laboratoire de Chimie des polymères organiques [LCPO] | |
| dc.contributor.author | DEFFIEUX, Alain | |
| hal.structure.identifier | Centre de Recherches sur les Macromolécules Végétales [CERMAV] | |
| dc.contributor.author | BORSALI, Redouane | |
| hal.structure.identifier | Laboratoire de Chimie des polymères organiques [LCPO] | |
| hal.structure.identifier | Team 2 LCPO : Biopolymers & Bio-sourced Polymers | |
| dc.contributor.author | CRAMAIL, Henri | |
| dc.date.accessioned | 2020 | |
| dc.date.available | 2020 | |
| dc.date.issued | 2008 | |
| dc.identifier.issn | 0141-8130 | |
| dc.identifier.uri | https://oskar-bordeaux.fr/handle/20.500.12278/20770 | |
| dc.description.abstractEn | The self-assembly in toulene of linear polystyrene functionalized in alpha-position by benzoic acid moieties into active micelle-like structures was exploited to trap trimethylaluminium and thus generate encapsulated methylaluminoxane-like species. These nanimicellar reactors were subsequently used as such or in the presence of free benzoic acid for supporting the tridentate bis(imino)pyridinyl iron catalyst for ethylene polymerization. In this way, high catalytic activities and polyethylenes (PEs) with unimodal chain distribution and controlled morphology Were obtained. Remarkably well-defined spherical PE beads with an average diameter of 2 mm were produced when free benzoic acid was added to the micellar polymeric supports. | |
| dc.language.iso | en | |
| dc.publisher | Elsevier | |
| dc.subject.en | AQUEOUS SYSTEMS | |
| dc.subject.en | POLYPROPYLENEOXIDE CHAINS | |
| dc.subject.en | ORGANIC SUPPORTS | |
| dc.subject.en | POLY(STYRENE-CO-DIVINYLBENZENE) BEADS | |
| dc.subject.en | TRANSFER RADICAL POLYMERIZATION | |
| dc.subject.en | STAR-LIKE POLYSTYRENES | |
| dc.subject.en | ETHYLENE POLYMERIZATION | |
| dc.subject.en | OLEFIN POLYMERIZATION | |
| dc.subject.en | METALLOCENE CATALYSTS | |
| dc.subject.en | NANOPARTICLES | |
| dc.title.en | Polymer micelles as supports for the production of millimetric polyethylene beads | |
| dc.type | Article de revue | |
| dc.subject.hal | Chimie/Polymères | |
| bordeaux.journal | International Journal of Biological Macromolecules | |
| bordeaux.page | 7321-7329 | |
| bordeaux.volume | 41 | |
| bordeaux.hal.laboratories | Laboratoire de Chimie des Polymères Organiques (LCPO) - UMR 5629 | * |
| bordeaux.issue | 20 | |
| bordeaux.institution | Bordeaux INP | |
| bordeaux.institution | Université de Bordeaux | |
| bordeaux.peerReviewed | oui | |
| hal.identifier | hal-00340665 | |
| hal.version | 1 | |
| hal.origin.link | https://hal.archives-ouvertes.fr//hal-00340665v1 | |
| bordeaux.COinS | ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=International%20Journal%20of%20Biological%20Macromolecules&rft.date=2008&rft.volume=41&rft.issue=20&rft.spage=7321-7329&rft.epage=7321-7329&rft.eissn=0141-8130&rft.issn=0141-8130&rft.au=BOUILHAC,%20C%C3%A9cile&CLOUTET,%20Eric&TATON,%20Daniel&DEFFIEUX,%20Alain&BORSALI,%20Redouane&rft.genre=article |
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