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Dienes polymerization in the presence of metal hydrides and triethylaluminum
dc.rights.license | open | |
hal.structure.identifier | Laboratoire de Chimie des polymères organiques [LCPO] | |
dc.contributor.author | LABBÉ, Amélie | |
hal.structure.identifier | Laboratoire de Chimie des polymères organiques [LCPO] | |
hal.structure.identifier | Team 1 LCPO : Polymerization Catalyses & Engineering | |
dc.contributor.author | CARLOTTI, Stéphane | |
hal.structure.identifier | Laboratoire de Chimie des polymères organiques [LCPO] | |
dc.contributor.author | SHCHEGLOVA, Larisa | |
hal.structure.identifier | Polymer Laboratory [BASF] | |
dc.contributor.author | DESBOIS, Philippe | |
hal.structure.identifier | Laboratoire de Chimie des polymères organiques [LCPO] | |
dc.contributor.author | DEFFIEUX, Alain | |
dc.date.accessioned | 2020 | |
dc.date.available | 2020 | |
dc.date.created | 2006 | |
dc.date.issued | 2006 | |
dc.identifier.issn | 0032-3861 | |
dc.identifier.uri | https://oskar-bordeaux.fr/handle/20.500.12278/20761 | |
dc.description.abstractEn | Butadiene and isoprene can be polymerized by potassium hydride in aromatic hydrocarbons at various temperatures and in short times. A first additive, triethylaluminum, is needed to favour the homogeneity of the initiating system in the solvent of reaction. The importance of a second additive, a potassium alkoxide, is discussed in terms of activation of the polymerization. Experimental parameters like temperature, initiator concentration, activator/initiator ratio and monomer concentration are also investigated with the aim to reach a high content of 1,4 units. Transfer reactions occur for isoprene even though a good control of the polymerization is obtained for butadiene. | |
dc.language.iso | en | |
dc.publisher | Elsevier | |
dc.title.en | Dienes polymerization in the presence of metal hydrides and triethylaluminum | |
dc.type | Article de revue | |
dc.identifier.doi | 10.1016/j.polymer.2006.03.078 | |
dc.subject.hal | Chimie/Polymères | |
bordeaux.journal | Polymer | |
bordeaux.page | 3734-3739 | |
bordeaux.volume | 47 | |
bordeaux.hal.laboratories | Laboratoire de Chimie des Polymères Organiques (LCPO) - UMR 5629 | * |
bordeaux.issue | 11 | |
bordeaux.institution | Bordeaux INP | |
bordeaux.institution | Université de Bordeaux | |
bordeaux.peerReviewed | oui | |
hal.identifier | hal-00342093 | |
hal.version | 1 | |
dc.subject.it | retarded anionic polymerization | |
dc.subject.it | dienes | |
dc.subject.it | alkali metal hydride | |
dc.subject.it | trialkylluminum | |
hal.origin.link | https://hal.archives-ouvertes.fr//hal-00342093v1 | |
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