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Biomimetic processes II. Carbocationic polymerization of isopentenyl alcohol: A model for the synthesis of natural rubber?

dc.rights.licenseopen
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
dc.contributor.authorFORESTIER, Thibault
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
dc.contributor.authorPASETTO, Pamela
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
hal.structure.identifierTeam 1 LCPO : Polymerization Catalyses & Engineering
dc.contributor.authorPERUCH, Frédéric
IDREF: 152900748
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
hal.structure.identifierTeam 1 LCPO : Polymerization Catalyses & Engineering
dc.contributor.authorDEFFIEUX, Alain
hal.structure.identifierUniv Akron, Dept Polymer Sci
dc.contributor.authorPUSKAS, Judit E.
dc.date.accessioned2020
dc.date.available2020
dc.date.issued2009
dc.identifier.issn0928-4931
dc.identifier.urihttps://oskar-bordeaux.fr/handle/20.500.12278/20714
dc.description.abstractEnNatural rubber (poly(1.4-cis-isoprene), NR), a polymer of considerable industrial importance due to its exceptional properties, is exclusively produced from the cultivation of Hevea brasiliensis. After numerous attempts by polymer chemists to try to synthesize polyisoprene with very similar structures. none have been produced that exhibit such excellent properties. In this paper we analyze a new bio-inspired route towards NR based oil the carbocationic polymerization of isopentenyl pyrophosphate (IPP) (the natural monomer) and its derivatives. We report in ail initial study, the carbocationic polymerization of isopentenyl alcohol (IPOH) under various polymerization conditions. It is shown that oligomers are produced via 1,2 addition and not via the expected 1,4 addition.
dc.language.isoen
dc.publisherElsevier
dc.subject.enmechanistic study
dc.subject.ennatural rubber
dc.subject.encationic polymerization
dc.subject.enisopentenyl alcohol
dc.title.enBiomimetic processes II. Carbocationic polymerization of isopentenyl alcohol: A model for the synthesis of natural rubber?
dc.typeArticle de revue
dc.identifier.doi10.1016/j.msec.2008.06.025
dc.subject.halChimie/Polymères
bordeaux.journalMaterials Science and Engineering: C
bordeaux.page357-362
bordeaux.volume29
bordeaux.hal.laboratoriesLaboratoire de Chimie des Polymères Organiques (LCPO) - UMR 5629*
bordeaux.issue2
bordeaux.institutionBordeaux INP
bordeaux.institutionUniversité de Bordeaux
bordeaux.peerReviewedoui
hal.identifierhal-00380385
hal.version1
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-00380385v1
bordeaux.COinSctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Materials%20Science%20and%20Engineering:%20C&rft.date=2009&rft.volume=29&rft.issue=2&rft.spage=357-362&rft.epage=357-362&rft.eissn=0928-4931&rft.issn=0928-4931&rft.au=FORESTIER,%20Thibault&PASETTO,%20Pamela&PERUCH,%20Fr%C3%A9d%C3%A9ric&DEFFIEUX,%20Alain&PUSKAS,%20Judit%20E.&rft.genre=article


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