Polymerization of hex-1-ene initiated by diimine complexes of nickel and palladium
| dc.rights.license | open | |
| hal.structure.identifier | Brno Univ Technol, Inst Mat Chem | |
| dc.contributor.author | MERNA, Jan | |
| hal.structure.identifier | Brno Univ Technol, Inst Mat Chem | |
| dc.contributor.author | CIHLAR, Jaroslav | |
| hal.structure.identifier | Brno Univ Technol, Inst Mat Chem | |
| dc.contributor.author | KUCERA, Miloslav | |
| hal.structure.identifier | Laboratoire de Chimie des polymères organiques [LCPO] | |
| hal.structure.identifier | Team 1 LCPO : Polymerization Catalyses & Engineering | |
| dc.contributor.author | DEFFIEUX, Alain | |
| hal.structure.identifier | Laboratoire de Chimie des polymères organiques [LCPO] | |
| hal.structure.identifier | Team 2 LCPO : Biopolymers & Bio-sourced Polymers | |
| dc.contributor.author | CRAMAIL, Henri | |
| dc.date.accessioned | 2020 | |
| dc.date.available | 2020 | |
| dc.date.issued | 2005 | |
| dc.identifier.issn | 0014-3057 | |
| dc.identifier.uri | https://oskar-bordeaux.fr/handle/20.500.12278/20695 | |
| dc.description.abstractEn | The effect of monomer concentration, reaction temperature and initiator structure on the activity, molar mass, branching and thermal properties of poly(hex-1-ene)s was investigated for the polymerization of hex-1-ene initiated by four alpha-diimine complexes of nickel and palladium. Hex-1-ene polymerization exhibits an apparent negative kinetic order with respect to monomer concentration. Polymerization of hex-1-ene initiated by MAO activated 1,4-bis(2, 6-diisopropylphenyl)acenaphtenediiminenickel(II) dibromide (1a/MAO) proceeds in living-like fashion not only at sub-zero temperatures but even at 20degreesC. However, molar masses of the polymers are higher than predicted values in agreement with an initiator efficiency lower than one. | |
| dc.language.iso | en | |
| dc.publisher | Elsevier | |
| dc.subject.en | polyolefins | |
| dc.subject.en | kinetics (polym.) | |
| dc.subject.en | structure | |
| dc.subject.en | nickel catalyst | |
| dc.subject.en | living polymerization | |
| dc.title.en | Polymerization of hex-1-ene initiated by diimine complexes of nickel and palladium | |
| dc.type | Article de revue | |
| dc.identifier.doi | 10.1016/j.europolymj.2004.09.013 | |
| dc.subject.hal | Chimie/Polymères | |
| bordeaux.journal | European Polymer Journal | |
| bordeaux.page | 303-312 | |
| bordeaux.volume | 41 | |
| bordeaux.hal.laboratories | Laboratoire de Chimie des Polymères Organiques (LCPO) - UMR 5629 | * |
| bordeaux.issue | 29 | |
| bordeaux.institution | Bordeaux INP | |
| bordeaux.institution | Université de Bordeaux | |
| bordeaux.peerReviewed | oui | |
| hal.identifier | hal-00393813 | |
| hal.version | 1 | |
| hal.origin.link | https://hal.archives-ouvertes.fr//hal-00393813v1 | |
| bordeaux.COinS | ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=European%20Polymer%20Journal&rft.date=2005&rft.volume=41&rft.issue=29&rft.spage=303-312&rft.epage=303-312&rft.eissn=0014-3057&rft.issn=0014-3057&rft.au=MERNA,%20Jan&CIHLAR,%20Jaroslav&KUCERA,%20Miloslav&DEFFIEUX,%20Alain&CRAMAIL,%20Henri&rft.genre=article |
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