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hal.structure.identifierLaboratoire de Chimie des polymères organiques [LCPO]
dc.contributor.authorCHAMBON, Pierre
hal.structure.identifierLaboratoire de Chimie des polymères organiques [LCPO]
hal.structure.identifierTeam 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
dc.contributor.authorCLOUTET, Eric
IDREF: 151048681
hal.structure.identifierLaboratoire de Chimie des polymères organiques [LCPO]
hal.structure.identifierTeam 2 LCPO : Biopolymers & Bio-sourced Polymers
dc.contributor.authorCRAMAIL, Henri
dc.date.accessioned2020
dc.date.available2020
dc.date.issued2005
dc.identifier.issn1022-1360
dc.identifier.urihttps://oskar-bordeaux.fr/handle/20.500.12278/20692
dc.description.abstractEnCore-shell polyurethane (PUR)-polydimethylsiloxane (PDMS) particles were prepared by polyaddition between ethylene glycol and tolylene-2,4-diisocyanate in cyclohexane, used as the organic dispersant phase, in the presence of reactive hydroxy-terminated polydimethylsiloxane steric stabilizers. The reaction extent and the PUR particle size, monitored by FTIR, H-1 NMR, SEC, SEM and TEM techniques against time, were found a function of the PDMS concentration, functionality and molar mass. A mechanism of the polyurethane particle growth is proposed on the grounds of the kinetic investigation.
dc.language.isoen
dc.publisherWiley-VCH Verlag
dc.subject.enpolyurethane
dc.subject.endispersion polymerization
dc.subject.enpolyaddition
dc.subject.enpolydimethylsiloxane
dc.subject.encore-shell particles
dc.title.enSynthesis of core-shell polyurethane-polydimethylsiloxane particles by polyaddition in organic dispersant media: Mechanism of particle formation
dc.typeArticle de revue
dc.identifier.doi10.1002/masy.200550821
dc.subject.halChimie/Polymères
bordeaux.journalMacromolecular Symposia
bordeaux.page227-238
bordeaux.volume226
bordeaux.hal.laboratoriesLaboratoire de Chimie des Polymères Organiques (LCPO) - UMR 5629*
bordeaux.institutionBordeaux INP
bordeaux.institutionUniversité de Bordeaux
bordeaux.peerReviewedoui
hal.identifierhal-00393818
hal.version1
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-00393818v1
bordeaux.COinSctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Macromolecular%20Symposia&rft.date=2005&rft.volume=226&rft.spage=227-238&rft.epage=227-238&rft.eissn=1022-1360&rft.issn=1022-1360&rft.au=CHAMBON,%20Pierre&CLOUTET,%20Eric&CRAMAIL,%20Henri&rft.genre=article


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