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Synthesis of core-shell polyurethane-polydimethylsiloxane particles by polyaddition in organic dispersant media: Mechanism of particle formation
| dc.rights.license | open | |
| hal.structure.identifier | Laboratoire de Chimie des polymères organiques [LCPO] | |
| dc.contributor.author | CHAMBON, Pierre | |
| hal.structure.identifier | Laboratoire de Chimie des polymères organiques [LCPO] | |
| hal.structure.identifier | Team 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies | |
| dc.contributor.author | CLOUTET, Eric
IDREF: 151048681 | |
| hal.structure.identifier | Laboratoire de Chimie des polymères organiques [LCPO] | |
| hal.structure.identifier | Team 2 LCPO : Biopolymers & Bio-sourced Polymers | |
| dc.contributor.author | CRAMAIL, Henri | |
| dc.date.accessioned | 2020 | |
| dc.date.available | 2020 | |
| dc.date.issued | 2005 | |
| dc.identifier.issn | 1022-1360 | |
| dc.identifier.uri | https://oskar-bordeaux.fr/handle/20.500.12278/20692 | |
| dc.description.abstractEn | Core-shell polyurethane (PUR)-polydimethylsiloxane (PDMS) particles were prepared by polyaddition between ethylene glycol and tolylene-2,4-diisocyanate in cyclohexane, used as the organic dispersant phase, in the presence of reactive hydroxy-terminated polydimethylsiloxane steric stabilizers. The reaction extent and the PUR particle size, monitored by FTIR, H-1 NMR, SEC, SEM and TEM techniques against time, were found a function of the PDMS concentration, functionality and molar mass. A mechanism of the polyurethane particle growth is proposed on the grounds of the kinetic investigation. | |
| dc.language.iso | en | |
| dc.publisher | Wiley-VCH Verlag | |
| dc.subject.en | polyurethane | |
| dc.subject.en | dispersion polymerization | |
| dc.subject.en | polyaddition | |
| dc.subject.en | polydimethylsiloxane | |
| dc.subject.en | core-shell particles | |
| dc.title.en | Synthesis of core-shell polyurethane-polydimethylsiloxane particles by polyaddition in organic dispersant media: Mechanism of particle formation | |
| dc.type | Article de revue | |
| dc.identifier.doi | 10.1002/masy.200550821 | |
| dc.subject.hal | Chimie/Polymères | |
| bordeaux.journal | Macromolecular Symposia | |
| bordeaux.page | 227-238 | |
| bordeaux.volume | 226 | |
| bordeaux.hal.laboratories | Laboratoire de Chimie des Polymères Organiques (LCPO) - UMR 5629 | * |
| bordeaux.institution | Bordeaux INP | |
| bordeaux.institution | Université de Bordeaux | |
| bordeaux.peerReviewed | oui | |
| hal.identifier | hal-00393818 | |
| hal.version | 1 | |
| hal.origin.link | https://hal.archives-ouvertes.fr//hal-00393818v1 | |
| bordeaux.COinS | ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Macromolecular%20Symposia&rft.date=2005&rft.volume=226&rft.spage=227-238&rft.epage=227-238&rft.eissn=1022-1360&rft.issn=1022-1360&rft.au=CHAMBON,%20Pierre&CLOUTET,%20Eric&CRAMAIL,%20Henri&rft.genre=article |
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