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Anionic high impact polystyrene: A new process for low residual and low cost HIPS

dc.rights.licenseopen
hal.structure.identifierPolymer Laboratory [BASF]
dc.contributor.authorDESBOIS, Philippe
hal.structure.identifierPolymer Laboratory [BASF]
dc.contributor.authorWARZELHAN, Volker
hal.structure.identifierPolymer Laboratory [BASF]
dc.contributor.authorNIESSNER, Norbert
hal.structure.identifierLaboratoire de Chimie des polymères organiques [LCPO]
dc.contributor.authorDEFFIEUX, Alain
hal.structure.identifierLaboratoire de Chimie des polymères organiques [LCPO]
hal.structure.identifierTeam 1 LCPO : Polymerization Catalyses & Engineering
dc.contributor.authorCARLOTTI, Stéphane
dc.date.accessioned2020
dc.date.available2020
dc.date.issued2006
dc.identifier.issn1022-1360
dc.identifier.urihttps://oskar-bordeaux.fr/handle/20.500.12278/20656
dc.description.abstractEnBASF has developed a new process for the manufacturing of High Impact Polystyrene (HIPS) via an anionic route: the so-called A-HIPS process. The driving forces were the development of a product with a low content of residuals and improved cost performance compared to the radical state of the art HIPS. The production of A-HIPS includes the synthesis of the rubber, a styrene-butadiene block copolymer. To overcome the main challenges of anionic polymerization such as reactivity control, solvent purity and initiator costs, BASF has developed its own proprietary technology, the Retarded Anionic Polymerization (R.A.P.) which allows styrene polymerization to 100% conversion under similar reaction conditions as the radical polymerization. A new low cost anionic initiator system (BuLi-free), based on sodium hydride and triethylaluminum, has been developed for perfect reactivity control over a broad temperature and concentration range even up to bulk conditions.
dc.language.isoen
dc.publisherWiley-VCH Verlag
dc.subject.enretarded anionic polymerization (RAP)
dc.subject.enhigh impact polystyrene
dc.subject.enprocessing
dc.subject.enanionic polymerization
dc.subject.enliving polymerization
dc.title.enAnionic high impact polystyrene: A new process for low residual and low cost HIPS
dc.typeArticle de revue
dc.identifier.doi10.1002/masy.200650824
dc.subject.halChimie/Polymères
bordeaux.journalMacromolecular Symposia
bordeaux.page194-205
bordeaux.volume240
bordeaux.hal.laboratoriesLaboratoire de Chimie des Polymères Organiques (LCPO) - UMR 5629*
bordeaux.institutionBordeaux INP
bordeaux.institutionUniversité de Bordeaux
bordeaux.peerReviewedoui
hal.identifierhal-00396159
hal.version1
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-00396159v1
bordeaux.COinSctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Macromolecular%20Symposia&rft.date=2006&rft.volume=240&rft.spage=194-205&rft.epage=194-205&rft.eissn=1022-1360&rft.issn=1022-1360&rft.au=DESBOIS,%20Philippe&WARZELHAN,%20Volker&NIESSNER,%20Norbert&DEFFIEUX,%20Alain&CARLOTTI,%20St%C3%A9phane&rft.genre=article


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