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Biomimetic Processes. IV. Carbocationic Polymerization of Isoprene Initiated by Dimethyl Allyl Alcohol

dc.rights.licenseopen
hal.structure.identifierUniv Akron, Dept Polymer Sci
dc.contributor.authorPUSKAS, Judit E.
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
dc.contributor.authorPERES, Clément
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
hal.structure.identifierTeam 1 LCPO : Polymerization Catalyses & Engineering
dc.contributor.authorPERUCH, Frédéric
IDREF: 152900748
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
hal.structure.identifierTeam 1 LCPO : Polymerization Catalyses & Engineering
dc.contributor.authorDEFFIEUX, Alain
hal.structure.identifierDepartment of Chemistry [Akron]
dc.contributor.authorDABNEY, David E.
hal.structure.identifierDepartment of Chemistry [Akron]
dc.contributor.authorWESDEMIOTIS, Chrys
hal.structure.identifierUniv Akron, Dept Polymer Sci
dc.contributor.authorHAYAT-SOYTAS, Serap
hal.structure.identifierAgnes Scott Coll, Decatur, GA
dc.contributor.authorLINDSAY, Allia
dc.date.accessioned2020
dc.date.available2020
dc.date.issued2009
dc.identifier.issn0887-624X
dc.identifier.urihttps://oskar-bordeaux.fr/handle/20.500.12278/20646
dc.description.abstractEnIn this article, we investigate a new bio-inspired synthetic route towards NR homologs based on the carbocationic polymerization of isoprene initiated by dimethyl allyl alcohol (DMAOH)/TiCl4 or BF3 center dot Et2O as the catalytic system. This study is the continuation of our studies related to the proof of principle that NR biosynthesis is based on a carbocationic mechanism. It is shown that using the biomimetic strategy of initiation by allylic carbocations, polyisoprene carrying a dimethyl allyl head group is produced almost exclusively via 1,4 addition, yielding repeating units with cis and trans configurations
dc.language.isoen
dc.publisherWiley
dc.subject.enreal-time FTIR
dc.subject.enpolyisoprene
dc.subject.enbiomimetic
dc.subject.enbiosynthesis
dc.subject.encationic polymerization
dc.subject.ennatural rubber
dc.title.enBiomimetic Processes. IV. Carbocationic Polymerization of Isoprene Initiated by Dimethyl Allyl Alcohol
dc.typeArticle de revue
dc.identifier.doi10.1002/pola.23293
dc.subject.halChimie/Polymères
bordeaux.journalJournal of Polymer Science Part A: Polymer Chemistry
bordeaux.page2181-2189
bordeaux.volume47
bordeaux.hal.laboratoriesLaboratoire de Chimie des Polymères Organiques (LCPO) - UMR 5629*
bordeaux.issue8
bordeaux.institutionBordeaux INP
bordeaux.institutionUniversité de Bordeaux
bordeaux.peerReviewedoui
hal.identifierhal-00397638
hal.version1
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-00397638v1
bordeaux.COinSctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Journal%20of%20Polymer%20Science%20Part%20A:%20Polymer%20Chemistry&rft.date=2009&rft.volume=47&rft.issue=8&rft.spage=2181-2189&rft.epage=2181-2189&rft.eissn=0887-624X&rft.issn=0887-624X&rft.au=PUSKAS,%20Judit%20E.&PERES,%20Cl%C3%A9ment&PERUCH,%20Fr%C3%A9d%C3%A9ric&DEFFIEUX,%20Alain&DABNEY,%20David%20E.&rft.genre=article


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