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High-temperature nitroxide-mediated radical polymerization in a continuous microtube reactor: Towards a better control of the polymerization reaction

dc.rights.licenseopen
dc.contributor.authorROSENFELD, Carine
dc.contributor.authorSERRA, Christophe
hal.structure.identifierTeam 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
dc.contributor.authorBROCHON, Cyril
hal.structure.identifierTeam 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
dc.contributor.authorHADZIIOANNOU, Georges
dc.date.accessioned2020
dc.date.available2020
dc.date.issued2007
dc.identifier.issn0009-2509
dc.identifier.urihttps://oskar-bordeaux.fr/handle/20.500.12278/20611
dc.description.abstractEnNitroxide-mediated radical polymerization (NMRP), in a continuous microtube reactor of 900 pm inner diameter, of styrene and n-butyl acrylate at high temperature has been performed. The influence of the microsystem reactor on the control of the polymerization reaction was investigated and compared to a conventional labscale batch reactor. The main advantage of this microsystern is its ability to handle highly exothermic chemical reactions because of its high surface to volume ratio and the possibility to carry out the polymerization process in homogeneous conditions due to its small characteristic length. The discrepancy between microtube and batch reactors increases as the exothermicity of the monomer increases. In almost all experiments, the microtube reactor gives smallest polydispersity indices. Thus, the use of microstructured reactors can significantly improve the control of the polymerization.
dc.language.isoen
dc.publisherElsevier
dc.subject.enbatch
dc.subject.enpolymerization
dc.subject.enhomogenization
dc.subject.enmicrofluidic
dc.subject.ennitroxide
dc.subject.endiffusion
dc.title.enHigh-temperature nitroxide-mediated radical polymerization in a continuous microtube reactor: Towards a better control of the polymerization reaction
dc.typeArticle de revue
dc.identifier.doi10.1016/j.ces.2006.12.074
dc.subject.halChimie/Polymères
bordeaux.journalChemical Engineering Science
bordeaux.page5245-5250
bordeaux.volume62
bordeaux.hal.laboratoriesLaboratoire de Chimie des Polymères Organiques (LCPO) - UMR 5629*
bordeaux.issue18-20
bordeaux.institutionBordeaux INP
bordeaux.institutionUniversité de Bordeaux
bordeaux.peerReviewedoui
hal.identifierhal-00402952
hal.version1
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-00402952v1
bordeaux.COinSctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Chemical%20Engineering%20Science&rft.date=2007&rft.volume=62&rft.issue=18-20&rft.spage=5245-5250&rft.epage=5245-5250&rft.eissn=0009-2509&rft.issn=0009-2509&rft.au=ROSENFELD,%20Carine&SERRA,%20Christophe&BROCHON,%20Cyril&HADZIIOANNOU,%20Georges&rft.genre=article


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