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Electronic transport properties aspects and structure of polymer-fullerene based organic semiconductors for photovoltaic devices

dc.rights.licenseopen
hal.structure.identifierLaboratoire d'Ingenierie des Polymères pour les Hautes Technologies
dc.contributor.authorADAMOPOULOS, G.
hal.structure.identifierInstitut d'Electronique du Solide et des Systèmes [InESS]
dc.contributor.authorHEISER, Thomas
hal.structure.identifierLaboratoire d'Ingenierie des Polymères pour les Hautes Technologies
dc.contributor.authorGIOVANELLA, U.
hal.structure.identifierInstitut d'Electronique du Solide et des Systèmes [InESS]
dc.contributor.authorOULD-SAAD, S.
hal.structure.identifierLaboratoire d'Ingenierie des Polymères pour les Hautes Technologies
dc.contributor.authorVAN DE WETERING, K.
hal.structure.identifierLaboratoire d'Ingenierie des Polymères pour les Hautes Technologies
hal.structure.identifierTeam 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
dc.contributor.authorBROCHON, Cyril
hal.structure.identifierDepartment of Physics [Thessaloniki]
dc.contributor.authorZORBA, T.
hal.structure.identifierDepartment of Physics [Thessaloniki]
dc.contributor.authorPARASKEVOPOULOS, K.M.
hal.structure.identifierLaboratoire d'Ingenierie des Polymères pour les Hautes Technologies
hal.structure.identifierTeam 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
dc.contributor.authorHADZIIOANNOU, Georges
dc.date.accessioned2020
dc.date.available2020
dc.date.issued2006
dc.identifier.issn0040-6090
dc.identifier.urihttps://oskar-bordeaux.fr/handle/20.500.12278/20607
dc.description.abstractEnA series of polystyrene (PS) and fullerene (C-60) based thin films containing from 23 to 60 wt.% in fullerene were investigated. Initially, the films were characterised by Fourier Transform Infrared Spectroscopy (FTIR) spectroscopy where the characteristic absorption bands of both the fullerene and the polystyrene were revealed. The additional characteristic absorption bands due the grafted fullerene to polystyrene were revealed as well. The relative peak intensities provided with qualitative information of the films stoichiometry in terms of the fullerene's amount that was grafted to polystyrene. The optical properties of the films were investigated by spectroscopic ellipsometry (SE). It was found that the increase of the fullerene's amount that was grafted to polystyrene results in an increase of the absorption coefficient a, refractive index n, extinction coefficient k as well as in the dielectric constant epsilon(proportional to) within the range between 2.4 and 2.8 for the lower and higher fullerene content, respectively. The films' J-V characteristics, of the space charge limited current (SCLC)) behaviour, showed increased currents with increasing the fullerene's content. The electron mobility was extracted and found to increase with increasing the fullerene amount, from 4 x 10(-9) cm(2) V/s to 2 x 10(-7) cm(2) V/s.
dc.language.isoen
dc.publisherElsevier
dc.subject.enspectroscopic ellipsometry
dc.subject.enFTIR
dc.subject.enspace charge limited current
dc.subject.enfullerene derivatives
dc.title.enElectronic transport properties aspects and structure of polymer-fullerene based organic semiconductors for photovoltaic devices
dc.typeArticle de revue
dc.identifier.doi10.1016/j.tsf.2005.12.029
dc.subject.halChimie/Polymères
bordeaux.journalThin Solid Films
bordeaux.page371-376
bordeaux.volume511-512
bordeaux.hal.laboratoriesLaboratoire de Chimie des Polymères Organiques (LCPO) - UMR 5629*
bordeaux.institutionBordeaux INP
bordeaux.institutionUniversité de Bordeaux
bordeaux.peerReviewedoui
hal.identifierhal-00403002
hal.version1
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-00403002v1
bordeaux.COinSctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Thin%20Solid%20Films&rft.date=2006&rft.volume=511-512&rft.spage=371-376&rft.epage=371-376&rft.eissn=0040-6090&rft.issn=0040-6090&rft.au=ADAMOPOULOS,%20G.&HEISER,%20Thomas&GIOVANELLA,%20U.&OULD-SAAD,%20S.&VAN%20DE%20WETERING,%20K.&rft.genre=article


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