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Polyisoprene-based block copolymers as supports for metallocene and post-metallocene catalytic systems toward ethylene polymerization

dc.rights.licenseopen
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
dc.contributor.authorHEURTEFEU, Bertrand
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
dc.contributor.authorORIOU, Jules
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
dc.contributor.authorIBARBOURE, Emmanuel
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
hal.structure.identifierTeam 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
dc.contributor.authorCLOUTET, Eric
IDREF: 151048681
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
hal.structure.identifierTeam 2 LCPO : Biopolymers & Bio-sourced Polymers
dc.contributor.authorCRAMAIL, Henri
dc.date.accessioned2020
dc.date.available2020
dc.date.created2011
dc.date.issued2011
dc.identifier.issn1144-0546
dc.identifier.urihttps://oskar-bordeaux.fr/handle/20.500.12278/20544
dc.description.abstractEnIn this work, we report how micellar structures obtained by the self-assembly in heptane of polyisoprene-block-poly(methyl methacrylate) (PI-b-PMMA) and polyisoprene-block-poly(ethylene oxide) (PI-b-PEO) can be effectively used as organic supports for ethylene polymerization catalyzed by metallocene and post-metallocene catalysts. The self-assembly in heptane of these block copolymers was demonstrated by means of dynamic light scattering and the influence of methylaluminoxane (MAO) on this self-assembly was analyzed. The so-formed assemblies, composed of either PMMA or PEO cores and PI corona, were used as organic supports for metallocene or post-metallocene catalysts with methylaluminoxane (MAO) as an activator, to produce micrometric polyethylene beads
dc.language.isoen
dc.publisherRoyal Society of Chemistry
dc.subject.enCOMPLEXES
dc.subject.enMICELLES
dc.subject.enORGANIC SUPPORTS
dc.subject.enOLEFIN POLYMERIZATION
dc.title.enPolyisoprene-based block copolymers as supports for metallocene and post-metallocene catalytic systems toward ethylene polymerization
dc.typeArticle de revue
dc.identifier.doi10.1039/c1nj20309f
dc.subject.halChimie/Polymères
bordeaux.journalNew Journal of Chemistry
bordeaux.page2322-2332
bordeaux.volume35
bordeaux.hal.laboratoriesLaboratoire de Chimie des Polymères Organiques (LCPO) - UMR 5629*
bordeaux.issue10
bordeaux.institutionBordeaux INP
bordeaux.institutionUniversité de Bordeaux
bordeaux.peerReviewedoui
hal.identifierhal-00677768
hal.version1
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-00677768v1
bordeaux.COinSctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=New%20Journal%20of%20Chemistry&rft.date=2011&rft.volume=35&rft.issue=10&rft.spage=2322-2332&rft.epage=2322-2332&rft.eissn=1144-0546&rft.issn=1144-0546&rft.au=HEURTEFEU,%20Bertrand&ORIOU,%20Jules&IBARBOURE,%20Emmanuel&CLOUTET,%20Eric&CRAMAIL,%20Henri&rft.genre=article


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