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Compatibilization Method Applied to the Chitosan-Acid Poly(L-lactide) Solution

dc.rights.licenseopen
hal.structure.identifierGroupe de Recherche en Sciences Pour l'Ingénieur - EA 4694 [GRESPI]
dc.contributor.authorSUYATMA, Nugraba Edhi
hal.structure.identifierGroupe de Recherche en Sciences Pour l'Ingénieur - EA 4694 [GRESPI]
dc.contributor.authorCOPINET, Alain
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
hal.structure.identifierTeam 2 LCPO : Biopolymers & Bio-sourced Polymers
dc.contributor.authorCOMA, Veronique
hal.structure.identifierGroupe de Recherche en Sciences Pour l'Ingénieur - EA 4694 [GRESPI]
dc.contributor.authorFRICOTEAUX, Florence
dc.date.accessioned2020
dc.date.available2020
dc.date.created2010
dc.date.issued2010
dc.identifier.issn0021-8995
dc.identifier.urihttps://oskar-bordeaux.fr/handle/20.500.12278/20520
dc.description.abstractEnWe are testing the compatibilization of the chitosan/PLA blends by addition of diisocyanate and at studying the effect of several MDI concentrations (0.5 and 2.5% of the global blend mass, w/w). To evaluate the MDI efficiency as a compatibilizer of chitosan/PLA blends, we worked with the following methods: IRTF spectra with higher peak at 1558 cm(-1) is due to the -NH bonds that exist in urea and urethane, thermal properties shows that the temperature of the endothermic peaks of the chitosan/PLA blends with MDI is very close to the temperature of pure chitosane and SEM micrography shows that MDI addition decreases the PLA particles size in the chitosan mixture; they also comply with the compatibilization theory. After that the mechanical properties have been characterized: we can notice that the MDI compatibilized chitosan/PLA blends have a higher Young's modulus than the noncompatibilized blends. we are showed that the use of 0.5% MDI is not enough sufficient to obtain a compatibilization, because a part of the MDI can be consumed by water. The addition of MDI increases the performance of the mechanical properties of the blends. Therefore, with this compatibilization, we could obtain some chitosan/PLA blends that would be water-resistant and that would also keep their mechanical properties
dc.language.isoen
dc.publisherWiley
dc.title.enCompatibilization Method Applied to the Chitosan-Acid Poly(L-lactide) Solution
dc.typeArticle de revue
dc.identifier.doi10.1002/app.32115
dc.subject.halChimie/Polymères
bordeaux.journalJournal of Applied Polymer Science
bordeaux.page3083-3091
bordeaux.volume117
bordeaux.hal.laboratoriesLaboratoire de Chimie des Polymères Organiques (LCPO) - UMR 5629*
bordeaux.issue5
bordeaux.institutionBordeaux INP
bordeaux.institutionUniversité de Bordeaux
bordeaux.peerReviewedoui
hal.identifierhal-00679390
hal.version1
dc.subject.itblend
dc.subject.itMDI
dc.subject.itPLA
dc.subject.itcompatibilization
dc.subject.itchitosan
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-00679390v1
bordeaux.COinSctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Journal%20of%20Applied%20Polymer%20Science&rft.date=2010&rft.volume=117&rft.issue=5&rft.spage=3083-3091&rft.epage=3083-3091&rft.eissn=0021-8995&rft.issn=0021-8995&rft.au=SUYATMA,%20Nugraba%20Edhi&COPINET,%20Alain&COMA,%20Veronique&FRICOTEAUX,%20Florence&rft.genre=article


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