Synthesis of Donor-Acceptor Multiblock Copolymers Incorporating Fullerene Backbone Repeat Units
dc.rights.license | open | |
hal.structure.identifier | Laboratoire de Chimie des Polymères Organiques [LCPO] | |
dc.contributor.author | HIORNS, Roger Clive | |
hal.structure.identifier | Laboratoire de Chimie des Polymères Organiques [LCPO] | |
hal.structure.identifier | Team 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies | |
dc.contributor.author | CLOUTET, Eric
IDREF: 151048681 | |
hal.structure.identifier | Laboratoire de Chimie des Polymères Organiques [LCPO] | |
dc.contributor.author | IBARBOURE, Emmanuel | |
dc.contributor.author | KHOUKH, Abdel | |
hal.structure.identifier | Laboratoire de l'intégration, du matériau au système [IMS] | |
dc.contributor.author | BEJBOUJI, Habiba | |
hal.structure.identifier | Laboratoire de l'intégration, du matériau au système [IMS] | |
dc.contributor.author | VIGNAU, Laurence | |
hal.structure.identifier | Laboratoire de Chimie des Polymères Organiques [LCPO] | |
hal.structure.identifier | Team 2 LCPO : Biopolymers & Bio-sourced Polymers | |
dc.contributor.author | CRAMAIL, Henri | |
dc.date.accessioned | 2020 | |
dc.date.available | 2020 | |
dc.date.issued | 2010 | |
dc.identifier.issn | 0024-9297 | |
dc.identifier.uri | https://oskar-bordeaux.fr/handle/20.500.12278/20504 | |
dc.description.abstractEn | The synthesis of the first example ()la block copolymer based on a polymer using fullerene as a backbone repeat subunit is demonstrated A facile route incorporating the electron acceptor and high fullerene content polymer, poly{(1,4-fullerene)-alt-[1,4-dimethylene-2,5-bis(cyclohexylmethylether)phenylene]} (PFDP), with the archetypal electron donor, poly(3-hexylthiophene) (P3HT), into a multiblock copolymer (M BC) structure is presented alpha,omega-Bromomethyl-PFDP was prepared by atom-transfer radical addition polymerization (ATRAP) and then reacted with alpha,omega-phenol-P3HT via a Williamson condensation to yield the MBCs The lengths of the electron-acceptor and donor polymer blocks could be selected so that the resulting solid state domains were of a size appropriate to organic solar cells Also 11 was found that the MBCs gave a wide range of macro-structures, from micelles to well-defined wires, depending on the preparation conditions. | |
dc.language.iso | en | |
dc.publisher | American Chemical Society | |
dc.subject.en | PLASTIC ELECTRONICS | |
dc.subject.en | TRIBLOCK COPOLYMERS | |
dc.subject.en | PHOTOVOLTAIC CELLS | |
dc.subject.en | COIL BLOCK-COPOLYMERS | |
dc.subject.en | INTERNAL QUANTUM EFFICIENCY | |
dc.subject.en | ORGANIC SOLAR-CELLS | |
dc.subject.en | MOLECULAR-WEIGHT | |
dc.subject.en | DIBLOCK COPOLYMERS | |
dc.subject.en | REGIOREGULAR POLY(3-HEXYLTHIOPHENE) | |
dc.subject.en | CONJUGATED POLYMERS | |
dc.title.en | Synthesis of Donor-Acceptor Multiblock Copolymers Incorporating Fullerene Backbone Repeat Units | |
dc.type | Article de revue | |
dc.identifier.doi | 10.1021/ma100694y | |
dc.subject.hal | Chimie/Polymères | |
bordeaux.journal | Macromolecules | |
bordeaux.page | 6033-6044 | |
bordeaux.volume | 43 | |
bordeaux.hal.laboratories | Laboratoire de Chimie des Polymères Organiques (LCPO) - UMR 5629 | * |
bordeaux.issue | 14 | |
bordeaux.institution | Bordeaux INP | |
bordeaux.institution | Université de Bordeaux | |
bordeaux.peerReviewed | oui | |
hal.identifier | hal-00679988 | |
hal.version | 1 | |
hal.origin.link | https://hal.archives-ouvertes.fr//hal-00679988v1 | |
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