Mostrar el registro sencillo del ítem

Synthesis of isosorbide based polyurethanes: An isocyanate free method

dc.rights.licenseopen
hal.structure.identifierInstitut Charles Gerhardt Montpellier - Institut de Chimie Moléculaire et des Matériaux de Montpellier [ICGM ICMMM]
dc.contributor.authorBESSE, Vincent
hal.structure.identifierInstitut Charles Gerhardt Montpellier - Institut de Chimie Moléculaire et des Matériaux de Montpellier [ICGM ICMMM]
dc.contributor.authorAUVERGNE, Rémi
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
hal.structure.identifierTeam 1 LCPO : Polymerization Catalyses & Engineering
dc.contributor.authorCARLOTTI, Stéphane
dc.contributor.authorBOUTEVIN, Gilles
hal.structure.identifierCentre des Matériaux des Mines d'Alès [C2MA]
dc.contributor.authorOTAZAGHINE, Belkacem
hal.structure.identifierInstitut Charles Gerhardt Montpellier - Institut de Chimie Moléculaire et des Matériaux de Montpellier [ICGM ICMMM]
dc.contributor.authorCAILLOL, Sylvain
hal.structure.identifierIngénierie des Matériaux Polymères - Laboratoire des Matériaux Macromoléculaires [IMP-LMM]
dc.contributor.authorPASCAULT, Jean-Pierre
hal.structure.identifierInstitut Charles Gerhardt Montpellier - Institut de Chimie Moléculaire et des Matériaux de Montpellier [ICGM ICMMM]
dc.contributor.authorBOUTEVIN, Bernard
dc.date.accessioned2020
dc.date.available2020
dc.date.created2012
dc.date.issued2013
dc.identifier.issn1381-5148
dc.identifier.urihttps://oskar-bordeaux.fr/handle/20.500.12278/20458
dc.description.abstractEnThe synthesis of isocyanate free polyurethanes is a major concern. This paper first reports the synthesis of new biobased isosorbide dicyclocarbonates from isosorbide. Then polyhydroxyurethanes (PHUs) were synthesized by a cyclocarbonate-amine step growth polyaddition with four commercial diamines (e.g. jeffamine D-400, 1,10 diaminodecane, diethylenetriamine and isophoronediamine). These unprecedented products, obtained with high yield, were characterized by 1H NMR, FTIR, DSC, SEC and TGA analyses. PHUs exhibited glass transition temperatures from 8 C to 59 C, and degradation temperatures (Td 5%) between 234 C and 255 C. Last but not least, the compounds produced during the degradation of these PHUs were analyzed by ATG-IR technique and showed that carbon dioxide and secondary amines are released.
dc.language.isoen
dc.publisherElsevier
dc.subject.enCarbonate
dc.subject.enThermal stability
dc.subject.enPolyhydroxyurethane
dc.subject.enIsosorbide
dc.subject.enRenewable resources
dc.title.enSynthesis of isosorbide based polyurethanes: An isocyanate free method
dc.typeArticle de revue
dc.identifier.doi10.1016/j.reactfunctpolym.2013.01.002
dc.subject.halChimie/Polymères
bordeaux.journalReactive and Functional Polymers
bordeaux.page588-594
bordeaux.volume73
bordeaux.hal.laboratoriesLaboratoire de Chimie des Polymères Organiques (LCPO) - UMR 5629*
bordeaux.institutionBordeaux INP
bordeaux.institutionUniversité de Bordeaux
bordeaux.peerReviewedoui
hal.identifierhal-00785178
hal.version1
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-00785178v1
bordeaux.COinSctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Reactive%20and%20Functional%20Polymers&rft.date=2013&rft.volume=73&rft.spage=588-594&rft.epage=588-594&rft.eissn=1381-5148&rft.issn=1381-5148&rft.au=BESSE,%20Vincent&AUVERGNE,%20R%C3%A9mi&CARLOTTI,%20St%C3%A9phane&BOUTEVIN,%20Gilles&OTAZAGHINE,%20Belkacem&rft.genre=article


Archivos en el ítem

ArchivosTamañoFormatoVer

No hay archivos asociados a este ítem.

Este ítem aparece en la(s) siguiente(s) colección(ones)

Mostrar el registro sencillo del ítem