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Polyether synthesis: From activated or metal-free anionic ring-opening polymerization of epoxides to functionalization

dc.rights.licenseopen
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
dc.contributor.authorBROCAS, Anne-Laure
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
dc.contributor.authorMANTZARIDIS, Christos
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
dc.contributor.authorTUNC, Deniz
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
hal.structure.identifierTeam 1 LCPO : Polymerization Catalyses & Engineering
dc.contributor.authorCARLOTTI, Stéphane
dc.date.accessioned2020
dc.date.available2020
dc.date.issued2013
dc.identifier.issn0079-6700
dc.identifier.urihttps://oskar-bordeaux.fr/handle/20.500.12278/20414
dc.description.abstractEnEpoxide derivatives constitute a broad family of monomers which are able to be polymerized by anionic or related nucleophilic ring-opening mechanism. The main synthetic strategies developed are reviewed in terms of polymerization rates, side reactions, and possibilities for controlling such polymerizations. Ring-opening polymerization of ethylene oxide and substituted epoxides utilizing alkali metal derivatives or other initiating systems in conjunction or not with activating systems are discussed. Emphasis is also given on the use of organic initiators or catalysts to trigger the metal-free ring-opening polymerization of epoxides. Functionalization of polyethers is also described, which includes the use of functional initiators, post-chemical modification of reactive functions carried by the polyether backbone, or functional-monomer insertion. A focus is particularly given on the preparation of polyethers bearing hydroxy, amine, allyl, azide and other reactive groups, at the chain ends or in the chains.
dc.language.isoen
dc.publisherElsevier
dc.subject.enEpoxides
dc.subject.enPolyether
dc.subject.enAnionic polymerization
dc.subject.enControlled/living polymerization
dc.subject.enRing-opening polymerization
dc.subject.enActivation
dc.subject.enFunctionalized polymers
dc.title.enPolyether synthesis: From activated or metal-free anionic ring-opening polymerization of epoxides to functionalization
dc.typeArticle de revue
dc.identifier.doi10.1016/j.progpolymsci.2012.09.007
dc.subject.halChimie/Polymères
bordeaux.journalProgress in Polymer Science
bordeaux.page845-873
bordeaux.volume38
bordeaux.hal.laboratoriesLaboratoire de Chimie des Polymères Organiques (LCPO) - UMR 5629*
bordeaux.issue6
bordeaux.institutionBordeaux INP
bordeaux.institutionUniversité de Bordeaux
bordeaux.peerReviewedoui
hal.identifierhal-00846238
hal.version1
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-00846238v1
bordeaux.COinSctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Progress%20in%20Polymer%20Science&rft.date=2013&rft.volume=38&rft.issue=6&rft.spage=845-873&rft.epage=845-873&rft.eissn=0079-6700&rft.issn=0079-6700&rft.au=BROCAS,%20Anne-Laure&MANTZARIDIS,%20Christos&TUNC,%20Deniz&CARLOTTI,%20St%C3%A9phane&rft.genre=article


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