Afficher la notice abrégée

Block Copolymer Systems: From Single Chain to Self-Assembled Nanostructures

dc.rights.licenseopen
hal.structure.identifierUniv Fed Alagoas UFAL
dc.contributor.authorGIACOMELLI, Cristiano
hal.structure.identifierUniv Fed Alagoas UFAL
dc.contributor.authorSCHMIDT, Vanessa
hal.structure.identifierCentre de Recherches sur les Macromolécules Végétales [CERMAV]
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
hal.structure.identifierTeam 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
dc.contributor.authorAISSOU, Karim
hal.structure.identifierCentre de Recherches sur les Macromolécules Végétales [CERMAV]
dc.contributor.authorBORSALI, Redouane
dc.date.accessioned2020
dc.date.available2020
dc.date.issued2010
dc.identifier.issn0743-7463
dc.identifier.urihttps://oskar-bordeaux.fr/handle/20.500.12278/20354
dc.description.abstractEnRecent advances in the field of macromolecular engineering applied to the fabrication of nanostructured materials using block copolymer chains as elementary building blocks are described in this feature article. By highlighting some of our work in the area and accounting for the contribution of other groups, we discuss the relationship between the physical-chemical properties of copolymer chains and the characteristics of nano-objects originating from their self-assembly in solution and in bulk, with emphasis on convenient strategies that allow for the control of composition, functionality, and topology at different levels of sophistication. In the case of micellar nanoparticles in solution, in particular, we present approaches leading to morphology selection via macromolecular architectural design, the functionalization of external solvent-philic shells with biomolecules (polysaccharides and proteins), and the maximization of micelle loading capacity by the suitable choice of solvent-phobic polymer segments. The fabrication of nanomaterials mediated by thin block copolymer films is also discussed. In this case, we emphasize the development of novel polymer chain manipulation strategies that ultimately allow for the preparation of precisely positioned nanodomains with a reduced number of defects a block-selective chemical reactivity. The challenges facing the soft matter community, the urgent demand to convert huge public and private investments into consumer products, and future possible directions in the field are also considered herein.
dc.language.isoen
dc.publisherAmerican Chemical Society
dc.subject.enMICELLES
dc.subject.enTHIN-FILMS
dc.subject.enPHASE-BEHAVIOR
dc.subject.enDIBLOCK COPOLYMER
dc.subject.enMICROPHASE SEPARATION
dc.subject.enSCATTERING PROPERTIES
dc.subject.enDYNAMIC SCATTERING
dc.subject.enSTRONG-SEGREGATION
dc.subject.enPOLYMERS
dc.subject.enLITHOGRAPHY
dc.title.enBlock Copolymer Systems: From Single Chain to Self-Assembled Nanostructures
dc.typeArticle de revue
dc.identifier.doi10.1021/1a100641j
dc.subject.halChimie/Polymères
bordeaux.journalLangmuir
bordeaux.page15734-15744
bordeaux.volume26
bordeaux.hal.laboratoriesLaboratoire de Chimie des Polymères Organiques (LCPO) - UMR 5629*
bordeaux.issue20
bordeaux.institutionBordeaux INP
bordeaux.institutionUniversité de Bordeaux
bordeaux.peerReviewedoui
hal.identifierhal-00950674
hal.version1
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-00950674v1
bordeaux.COinSctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Langmuir&rft.date=2010&rft.volume=26&rft.issue=20&rft.spage=15734-15744&rft.epage=15734-15744&rft.eissn=0743-7463&rft.issn=0743-7463&rft.au=GIACOMELLI,%20Cristiano&SCHMIDT,%20Vanessa&AISSOU,%20Karim&BORSALI,%20Redouane&rft.genre=article


Fichier(s) constituant ce document

FichiersTailleFormatVue

Il n'y a pas de fichiers associés à ce document.

Ce document figure dans la(les) collection(s) suivante(s)

Afficher la notice abrégée