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hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
hal.structure.identifierTeam 1 LCPO : Polymerization Catalyses & Engineering
dc.contributor.authorREGLERO RUIZ, José Antonio
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
hal.structure.identifierTeam 1 LCPO : Polymerization Catalyses & Engineering
dc.contributor.authorDUMON, Michel
hal.structure.identifierUniv Valladolid, Dept Condensed Matter Phys
dc.contributor.authorPINTO, Javier
hal.structure.identifierUniv Valladolid, Dept Condensed Matter Phys
dc.contributor.authorRODRIGUEZ PEREZ, Miguel Angel
dc.date.accessioned2020
dc.date.available2020
dc.date.issued2011
dc.identifier.issn1438-7492
dc.identifier.urihttps://oskar-bordeaux.fr/handle/20.500.12278/20340
dc.description.abstractEnA new type of nanocellular polymeric material based on PMMA and a MAM triblock copolymer is presented. The production avoids the use of physical additives and leads to completely homogeneous nanostructured polymers with a large number of CO2 nucleation sites. The foamed materials show average cell sizes <200nm and relative foam densities of 0.4, presenting a homogeneous cell structure. A physical effect not measured before in nanocellular materials is demonstrated, which leads to an increase of the glass transition temperature due to the confining effect of PMMA chains in the cell walls of the nanocellular foam. The effects of changing saturation pressure and MAM content in the cellular structure are described, together with three-point bending Young's modulus measured using DMA.
dc.language.isoen
dc.publisherWiley-VCH Verlag
dc.subject.encarbon dioxide
dc.subject.enfoams
dc.subject.enmorphology
dc.subject.ennanocellular
dc.subject.enpolymers
dc.title.enLow-Density Nanocellular Foams Produced by High-Pressure Carbon Dioxide
dc.typeArticle de revue
dc.identifier.doi10.1002/mame.201000346
dc.subject.halChimie/Polymères
bordeaux.journalMacromolecular Materials and Engineering
bordeaux.page752-759
bordeaux.volume296
bordeaux.hal.laboratoriesLaboratoire de Chimie des Polymères Organiques (LCPO) - UMR 5629*
bordeaux.issue8
bordeaux.institutionBordeaux INP
bordeaux.institutionUniversité de Bordeaux
bordeaux.peerReviewedoui
hal.identifierhal-00956655
hal.version1
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-00956655v1
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