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Archimedean Tilings and Hierarchical Lamellar Morphology Formed by Semicrystalline Miktoarm Star Terpolymer Thin Films
dc.rights.license | open | |
hal.structure.identifier | Laboratoire de Chimie des Polymères Organiques [LCPO] | |
hal.structure.identifier | Team 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies | |
dc.contributor.author | AISSOU, Karim | |
hal.structure.identifier | Laboratoire de Chimie des Polymères Organiques [LCPO] | |
dc.contributor.author | KWON, Wonsang | |
hal.structure.identifier | Laboratoire de Chimie des Polymères Organiques [LCPO] | |
hal.structure.identifier | Team 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies | |
dc.contributor.author | MUMTAZ, Muhammad | |
hal.structure.identifier | Laboratoire de Chimie des Polymères Organiques [LCPO] | |
hal.structure.identifier | Team 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies | |
dc.contributor.author | ANTOINE, Ségolène | |
dc.contributor.author | MARET, Mireille | |
hal.structure.identifier | Univ Groningen, Zernike Inst Adv Mat, Macromol Chem & New Polym Mat | |
dc.contributor.author | PORTALE, Giuseppe | |
hal.structure.identifier | Laboratoire de Chimie des Polymères Organiques [LCPO] | |
hal.structure.identifier | Team 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies | |
dc.contributor.author | FLEURY, Guillaume | |
hal.structure.identifier | Laboratoire de Chimie des Polymères Organiques [LCPO] | |
hal.structure.identifier | Team 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies | |
dc.contributor.author | HADZIIOANNOU, Georges | |
dc.date.accessioned | 2020 | |
dc.date.available | 2020 | |
dc.date.issued | 2016 | |
dc.identifier.issn | 1936-0851 | |
dc.identifier.uri | https://oskar-bordeaux.fr/handle/20.500.12278/20219 | |
dc.description.abstractEn | 3-Miktoarm star terpolymer architecture provides a window of opportunity in the design of complex "three-colored" patterns at the nanometer scale. Here, the directed self-assembly (DSA) of 3-miktoarm star terpolymer (poly(1, 1-dimethyl silacydobutane)-arm-polystyrene-armpoly(D,L-lactide acid)) (PDMSB-arm-PS-arm-PLA, noted hereafter 3 mu-DSL) into a hierarchical lamellar morphology is described. Excellent orientational order has been achieved by templating the asymmetric hierarchical lamellar morphology with topographical substrates. Increasing the PLA volume fraction leads to the formation of a hexagonal [6.6.6] Archimedean tiling which coexists with a metastable square symmetry [4.8.8] tiling stabilized by the step between terraces. Stability of the [6.6.6] tiling over the [4.8.8] one is also demonstrated with GISAXS measurements. | |
dc.language.iso | en | |
dc.publisher | American Chemical Society | |
dc.subject.en | Archimedean tiling | |
dc.subject.en | hierarchical lamellar pattern | |
dc.subject.en | directed self-assembly | |
dc.subject.en | 3-miktoarm star terpolymer | |
dc.subject.en | HETEROARM | |
dc.subject.en | TOMOGRAPHY | |
dc.subject.en | POLYSTYRENE | |
dc.subject.en | POLYMERS | |
dc.subject.en | topographical substrate | |
dc.subject.en | SHAPED TERPOLYMERS | |
dc.subject.en | COPOLYMER | |
dc.subject.en | SQUARE | |
dc.title.en | Archimedean Tilings and Hierarchical Lamellar Morphology Formed by Semicrystalline Miktoarm Star Terpolymer Thin Films | |
dc.type | Article de revue | |
dc.identifier.doi | 10.1021/acsnano.5b06728 | |
dc.subject.hal | Chimie/Polymères | |
bordeaux.journal | ACS Nano | |
bordeaux.page | 4055-4061 | |
bordeaux.volume | 10 | |
bordeaux.hal.laboratories | Laboratoire de Chimie des Polymères Organiques (LCPO) - UMR 5629 | * |
bordeaux.issue | 4 | |
bordeaux.institution | Bordeaux INP | |
bordeaux.institution | Université de Bordeaux | |
bordeaux.peerReviewed | oui | |
hal.identifier | hal-01369604 | |
hal.version | 1 | |
hal.origin.link | https://hal.archives-ouvertes.fr//hal-01369604v1 | |
bordeaux.COinS | ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=ACS%20Nano&rft.date=2016&rft.volume=10&rft.issue=4&rft.spage=4055-4061&rft.epage=4055-4061&rft.eissn=1936-0851&rft.issn=1936-0851&rft.au=AISSOU,%20Karim&KWON,%20Wonsang&MUMTAZ,%20Muhammad&ANTOINE,%20S%C3%A9gol%C3%A8ne&MARET,%20Mireille&rft.genre=article |
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