Protonated Phosphazenes: Structures and Hydrogen-Bonding Organocatalysts for Carbonyl Bond Activation
| dc.rights.license | open | |
| hal.structure.identifier | Institut des Sciences Moléculaires [ISM] | |
| dc.contributor.author | JARDEL, Damien | |
| hal.structure.identifier | Institut des Sciences Moléculaires [ISM] | |
| dc.contributor.author | DAVIES, Clotilde | |
| hal.structure.identifier | Laboratoire de Chimie des Polymères Organiques [LCPO] | |
| hal.structure.identifier | Team 1 LCPO : Polymerization Catalyses & Engineering | |
| dc.contributor.author | PERUCH, Frédéric
IDREF: 152900748 | |
| dc.contributor.author | MASSIP, Stéphane | |
| hal.structure.identifier | Institut des Sciences Moléculaires [ISM] | |
| dc.contributor.author | BIBAL, Brigitte | |
| dc.date.accessioned | 2020 | |
| dc.date.available | 2020 | |
| dc.date.issued | 2016 | |
| dc.identifier.issn | 1615-4150 | |
| dc.identifier.uri | https://oskar-bordeaux.fr/handle/20.500.12278/20193 | |
| dc.description.abstractEn | The synthesis and application of protonated phosphazeniums as hydrogen-bond donor groups was demonstrated in the solid state and in solution. In particular, their catalytic activity was shown in the activation of the carbonyl group within cyclic esters, using a benchmark reaction, that is, in the ring-opening polymerization of lactide and valerolactone, in the presence of a basic co-catalyst. The reactions proceed differently depending on monomers and/or phosphazenium salts. The impact of catalysts and reactants steric hindrance upon the outcome of the reaction is then highlighted and discussed. | |
| dc.language.iso | en | |
| dc.publisher | Wiley-VCH Verlag | |
| dc.subject.en | T-BU-P4 BASE | |
| dc.subject.en | ETHYLENE-OXIDE | |
| dc.subject.en | PHOSPHORUS CENTER | |
| dc.subject.en | P4-PHOSPHAZENE BASE | |
| dc.subject.en | ANIONIC-POLYMERIZATION | |
| dc.subject.en | UNCHARGED AUXILIARY BASES | |
| dc.subject.en | RING-OPENING POLYMERIZATION | |
| dc.subject.en | phosphazenium | |
| dc.subject.en | organocatalysis | |
| dc.subject.en | carbonyl activation | |
| dc.subject.en | hydrogen bond | |
| dc.subject.en | LACTIDE | |
| dc.subject.en | FUNCTIONALIZATION | |
| dc.subject.en | CATALYSTS | |
| dc.title.en | Protonated Phosphazenes: Structures and Hydrogen-Bonding Organocatalysts for Carbonyl Bond Activation | |
| dc.type | Article de revue | |
| dc.identifier.doi | 10.1002/adsc.201600062 | |
| dc.subject.hal | Chimie/Polymères | |
| bordeaux.journal | Advanced Synthesis and Catalysis | |
| bordeaux.page | 1110-1118 | |
| bordeaux.volume | 358 | |
| bordeaux.hal.laboratories | Laboratoire de Chimie des Polymères Organiques (LCPO) - UMR 5629 | * |
| bordeaux.issue | 7 | |
| bordeaux.institution | Bordeaux INP | |
| bordeaux.institution | Université de Bordeaux | |
| bordeaux.peerReviewed | oui | |
| hal.identifier | hal-01373045 | |
| hal.version | 1 | |
| hal.origin.link | https://hal.archives-ouvertes.fr//hal-01373045v1 | |
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