Do charges delocalize over multiple molecules in fullerene derivatives?
| dc.rights.license | open | |
| hal.structure.identifier | Univ Mons, Lab Chem Novel Mat, Belgium | |
| dc.contributor.author | D'AVINO, Gabriele | |
| hal.structure.identifier | Univ Mons, Lab Chem Novel Mat, Belgium | |
| dc.contributor.author | OLIVIER, Yoann | |
| hal.structure.identifier | Laboratoire de Chimie des Polymères Organiques [LCPO] | |
| hal.structure.identifier | Team 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies | |
| dc.contributor.author | MUCCIOLI, Luca | |
| hal.structure.identifier | Univ Mons, Lab Chem Novel Mat, Belgium | |
| dc.contributor.author | BELJONNE, David | |
| dc.date.accessioned | 2020 | |
| dc.date.available | 2020 | |
| dc.date.issued | 2016 | |
| dc.identifier.issn | 2050-7526 | |
| dc.identifier.uri | https://oskar-bordeaux.fr/handle/20.500.12278/20158 | |
| dc.description.abstractEn | We address the question of charge delocalization in amorphous and crystalline fullerene solids by performing state of the art calculations encompassing force-field molecular dynamics, microelectrostatic and quantum-chemical methods. The solution of a tight-binding model built from spatially (down to atomistic scale) and time (down to fs) resolved calculations yields the density of electronic states for the charge carriers and their energy-dependent intermolecular delocalization. Both pristine C-60 and the soluble PC61BM/PC71BM acceptors may sustain high-energy states that spread over a few tens of molecules irrespective of morphology, yet electrostatic disorder (mostly dipolar and static in nature) makes the thermally available electron states collapse to hardly more than one molecule in PC61BM/PC71BM, while it has a much more limited impact in the case of the bare C-60. Implications of these results for charge transport and exciton dissociation at donor-fullerene interfaces are discussed. | |
| dc.language.iso | en | |
| dc.publisher | Royal Society of Chemistry | |
| dc.subject.en | ACID METHYL-ESTER | |
| dc.subject.en | ORGANIC PHOTOVOLTAIC CELLS | |
| dc.subject.en | FIELD-EFFECT TRANSISTORS | |
| dc.subject.en | C-60 SINGLE-CRYSTALS | |
| dc.subject.en | POLARIZATION ENERGY | |
| dc.subject.en | ELECTRON-TRANSPORT | |
| dc.subject.en | SOLAR-CELLS | |
| dc.subject.en | LOCALIZED CHARGE | |
| dc.subject.en | HOPPING MODELS | |
| dc.subject.en | TRANSFER STATE | |
| dc.title.en | Do charges delocalize over multiple molecules in fullerene derivatives? | |
| dc.type | Article de revue | |
| dc.identifier.doi | 10.1039/c5tc03283k | |
| dc.subject.hal | Chimie/Polymères | |
| bordeaux.journal | Journal of Materials Chemistry C | |
| bordeaux.page | 3747-3756 | |
| bordeaux.volume | 4 | |
| bordeaux.hal.laboratories | Laboratoire de Chimie des Polymères Organiques (LCPO) - UMR 5629 | * |
| bordeaux.issue | 17 | |
| bordeaux.institution | Bordeaux INP | |
| bordeaux.institution | Université de Bordeaux | |
| bordeaux.peerReviewed | oui | |
| hal.identifier | hal-01416117 | |
| hal.version | 1 | |
| hal.origin.link | https://hal.archives-ouvertes.fr//hal-01416117v1 | |
| bordeaux.COinS | ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Journal%20of%20Materials%20Chemistry%20C&rft.date=2016&rft.volume=4&rft.issue=17&rft.spage=3747-3756&rft.epage=3747-3756&rft.eissn=2050-7526&rft.issn=2050-7526&rft.au=D'AVINO,%20Gabriele&OLIVIER,%20Yoann&MUCCIOLI,%20Luca&BELJONNE,%20David&rft.genre=article |
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