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Carbazole-based pi-conjugated polyazomethines: Effects of catenation and comonomer insertion on optoelectronic features

dc.rights.licenseopen
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
hal.structure.identifierTeam 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
dc.contributor.authorGARBAY, Guillaume
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
hal.structure.identifierTeam 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
hal.structure.identifierDepartment of Industrial Chemistry
dc.contributor.authorMUCCIOLI, Luca
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
hal.structure.identifierTeam 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
dc.contributor.authorPAVLOPOULOU, Eleni
dc.contributor.authorHANIFA, Amine
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
hal.structure.identifierTeam 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
dc.contributor.authorHADZIIOANNOU, Georges
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
hal.structure.identifierTeam 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
dc.contributor.authorBROCHON, Cyril
hal.structure.identifierTeam 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
dc.contributor.authorCLOUTET, Eric
IDREF: 151048681
dc.date.accessioned2020
dc.date.available2020
dc.date.issued2017
dc.identifier.issn0032-3861
dc.identifier.urihttps://oskar-bordeaux.fr/handle/20.500.12278/20119
dc.description.abstractEnA series of carbazole-based polyazomethines have been synthesized under micro-wave irradiation and without transition-metal based catalyst. The impact of both the catenation brought by the carbazole subunits and the insertion of a co-monomer, i.e. 3,4 ethylene dioxythiophene (EDOT), on the optical and electrochemical properties have been studied. Among the different polyazomethines synthesized, the best in terms of optical and electrochemical properties has been found to be the one with the azomethine function linked in positions 2,7 of carbazole subunits. Upon the insertion of the EDOT comonomer, an increase of the molecular weight and a red-shift in the absorption spectra has been observed, corresponding to a diminution of the electronic gap.
dc.language.isoen
dc.publisherElsevier
dc.subject.enorganic electronics
dc.subject.enpolyazomethines
dc.subject.encarbazole
dc.subject.encopolymer
dc.title.enCarbazole-based pi-conjugated polyazomethines: Effects of catenation and comonomer insertion on optoelectronic features
dc.typeArticle de revue
dc.identifier.doi10.1016/j.polymer.2017.05.039
dc.subject.halChimie/Polymères
dc.subject.halSciences de l'ingénieur [physics]
bordeaux.journalPolymer
bordeaux.page274-284
bordeaux.volume119
bordeaux.hal.laboratoriesLaboratoire de Chimie des Polymères Organiques (LCPO) - UMR 5629*
bordeaux.institutionBordeaux INP
bordeaux.institutionUniversité de Bordeaux
bordeaux.peerReviewedoui
hal.identifierhal-01528465
hal.version1
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-01528465v1
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