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Update and challenges in organo-mediated polymerization reactions

dc.rights.licenseopen
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
dc.contributor.authorOTTOU, Winnie Nzahou
hal.structure.identifierInstitute for Polymer Materials [POLYMAT]
dc.contributor.authorSARDON, Haritz
dc.contributor.authorMECERREYES, David
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
hal.structure.identifierTeam 1 LCPO : Polymerization Catalyses & Engineering
dc.contributor.authorVIGNOLLE, Joan
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
hal.structure.identifierTeam 1 LCPO : Polymerization Catalyses & Engineering
dc.contributor.authorTATON, Daniel
dc.date.accessioned2020
dc.date.available2020
dc.date.issued2016
dc.identifier.issn0079-6700
dc.identifier.urihttps://oskar-bordeaux.fr/handle/20.500.12278/20024
dc.description.abstractEnOrganocatalysis has become a very powerful tool for precision macromolecular chemistry, as judged by the number of articles published in this field in the past decade. A variety of small organic molecules, including Bronsted/Lewis bases and acids, based on amines, phosphines or carbenes, but also on bi-component systems, have been employed as a means to catalyze the polymerization of miscellaneous monomers. Not only can organocatalysts be employed to promote the ring-opening polymerization of various heterocyclics (e.g. lactones, lactide, cyclic carbonates, epoxides, lactams, cyclocarbosiloxanes), but some of them also allow activating vinylic monomers such as (meth)acrylics, or triggering the step growth polymerization of monomers such as diisocyanates and diols for polyurethane synthesis. The reduced toxicity of organocatalysts in comparison to their metallic counterparts is also driving their development in some sensitive applications, such as biomedical or microelectronics. Overall, organocatalysts display specific monomer activation modes, thereby providing a unique opportunity to control the polymerization of various functional monomers, under mild conditions. This review article focuses on advances of the past 4 years (>150 publications) in polymerization reactions utilizing small organic molecules either as direct initiators or as true catalysts, with a special emphasis on monomer activation modes, as well as polymerization mechanism aspects.
dc.description.sponsorshipPOLYMERISATIONS ORGANOCATALYSEES PAR LES CARBENES : VERS UNE PLATEFORME CATALYTIQUE MULTI-TACHE - ANR-11-BS08-0011
dc.language.isoen
dc.publisherElsevier
dc.subject.enBifunctional activation
dc.subject.enDirect initiation
dc.subject.enOrganic catalyst
dc.subject.enRing-opening polymerization
dc.subject.enStep-growth polymerization
dc.subject.enGroup transfer polymerization
dc.subject.enAcid catalysis
dc.subject.enBasic catalysis
dc.title.enUpdate and challenges in organo-mediated polymerization reactions
dc.typeArticle de revue
dc.identifier.doi10.1016/j.progpolymsci.2015.12.001
dc.subject.halChimie/Polymères
dc.description.sponsorshipEuropeEuropean Joint Doctorate in Organocatalysis and Sustainable Polymers
bordeaux.journalProgress in Polymer Science
bordeaux.page64-115
bordeaux.volume56
bordeaux.hal.laboratoriesLaboratoire de Chimie des Polymères Organiques (LCPO) - UMR 5629*
bordeaux.institutionBordeaux INP
bordeaux.institutionUniversité de Bordeaux
bordeaux.peerReviewedoui
hal.identifierhal-01366512
hal.version1
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-01366512v1
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