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Speciation of organic fraction does matter for source apportionment. Part 1 : A one-year campaign in Grenoble (France)

dc.rights.licenseopenen_US
hal.structure.identifierLaboratoire de Physico et Toxico-Chimie des systèmes naturels [LPTC]
hal.structure.identifierEnvironnements et Paléoenvironnements OCéaniques [EPOC]
hal.structure.identifierInstitut National de l'Environnement Industriel et des Risques [INERIS]
dc.contributor.authorSRIVASTAVA, Deepchandra
hal.structure.identifierLaboratoire de Physico et Toxico-Chimie des systèmes naturels [LPTC]
hal.structure.identifierEnvironnements et Paléoenvironnements OCéaniques [EPOC]
hal.structure.identifierInstitut National de l'Environnement Industriel et des Risques [INERIS]
dc.contributor.authorTOMAZ, Sophie
hal.structure.identifierInstitut National de l'Environnement Industriel et des Risques [INERIS]
dc.contributor.authorFAVEZ, Olivier
hal.structure.identifierInstitut National de l'Environnement Industriel et des Risques [INERIS]
dc.contributor.authorLANZAFAME, Grazia-Maria
hal.structure.identifierLaboratoire de Chimie Moléculaire et Environnement [LCME]
hal.structure.identifierInstitut des Géosciences de l’Environnement [IGE]
dc.contributor.authorGOLLY, Benjamin
hal.structure.identifierLaboratoire de Chimie Moléculaire et Environnement [LCME]
dc.contributor.authorBESOMBES, Jean-Luc
hal.structure.identifierCentre for Energy and Environment [CERI EE - IMT Nord Europe]
dc.contributor.authorALLEMAN, Laurent
hal.structure.identifierInstitut des Géosciences de l’Environnement [IGE]
dc.contributor.authorJAFFREZO, Jean-Luc
hal.structure.identifierInstitut des Géosciences de l’Environnement [IGE]
dc.contributor.authorJACOB, Véronique
hal.structure.identifierLaboratoire de Physico et Toxico-Chimie des systèmes naturels [LPTC]
hal.structure.identifierEnvironnements et Paléoenvironnements OCéaniques [EPOC]
dc.contributor.authorPERRAUDIN, Emilie
hal.structure.identifierLaboratoire de Physico et Toxico-Chimie des systèmes naturels [LPTC]
hal.structure.identifierEnvironnements et Paléoenvironnements OCéaniques [EPOC]
dc.contributor.authorVILLENAVE, Eric
hal.structure.identifierInstitut National de l'Environnement Industriel et des Risques [INERIS]
dc.contributor.authorALBINET, Alexandre
dc.date.accessioned2024-05-17T11:24:16Z
dc.date.available2024-05-17T11:24:16Z
dc.date.issued2018
dc.identifier.issn0048-9697en_US
dc.identifier.urihttps://oskar-bordeaux.fr/handle/20.500.12278/199920
dc.description.abstractEnPM10 source apportionment was performed by positive matrix factorization (PMF) using specific primary and secondary organic molecular markers on samples collected over a one year period (2013) at an urban station in Grenoble (France). The results provided a 9-factor optimum solution, including sources rarely apportioned in the literature, such as two types of primary biogenic organic aerosols (fungal spores and plant debris), as well as specific biogenic and anthropogenic secondary organic aerosols (SOA). These sources were identified thanks to the use of key organic markers, namely, polyols, odd number higher alkanes, and several SOA markers related to the oxidation of isoprene, α-pinene, toluene and polycyclic aromatic hydrocarbons (PAHs). Primary and secondary biogenic contributions together accounted for at least 68% of the total organic carbon (OC) in the summer, while anthropogenic primary and secondary sources represented at least 71% of OC during wintertime. A very significant contribution of anthropogenic SOA was estimated in the winter during an intense PM pollution event (PM10 > 50 μg m− 3 for several days; 18% of PM10 and 42% of OC). Specific meteorological conditions with a stagnation of pollutants over 10 days and possibly Fenton-like chemistry and self-amplification cycle of SOA formation could explain such high anthropogenic SOA concentrations during this period. Finally, PMF outputs were also used to investigate the origins of humic-like substances (HuLiS), which represented 16% of OC on an annual average basis. The results indicated that HuLiS were mainly associated with biomass burning (22%), secondary inorganic (22%), mineral dust (15%) and biogenic SOA (14%) factors. This study is probably the first to state that HuLiS are significantly associated with mineral dust.
dc.language.isoENen_US
dc.subjectAerosol
dc.subjectSource apportionment
dc.subjectPrimary biogenic organics
dc.subjectSOA
dc.subjectMolecular markers
dc.subjectHuLiS.
dc.title.enSpeciation of organic fraction does matter for source apportionment. Part 1 : A one-year campaign in Grenoble (France)
dc.typeArticle de revueen_US
dc.identifier.doi10.1016/j.scitotenv.2017.12.135en_US
dc.subject.halSciences de l'environnementen_US
bordeaux.journalScience of the Total Environmenten_US
bordeaux.page1598-1611en_US
bordeaux.volume624en_US
bordeaux.hal.laboratoriesEPOC : Environnements et Paléoenvironnements Océaniques et Continentaux - UMR 5805en_US
bordeaux.institutionUniversité de Bordeauxen_US
bordeaux.institutionCNRSen_US
bordeaux.teamLPTCen_US
bordeaux.peerReviewedouien_US
bordeaux.inpressnonen_US
bordeaux.import.sourcehal
hal.identifierineris-01853324
hal.version1
hal.popularnonen_US
hal.audienceInternationaleen_US
hal.exportfalse
workflow.import.sourcehal
dc.rights.ccPas de Licence CCen_US
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