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hal.structure.identifierIngénierie des Matériaux Polymères [IMP]
dc.contributor.authorOURDOUILLIE, Pascal
hal.structure.identifierIngénierie des Matériaux Polymères - Laboratoire des Matériaux Polymères et des Biomatériaux [IMP-LMPB]
dc.contributor.authorCHAUMONT, Philippe
hal.structure.identifierIngénierie des Matériaux Polymères [IMP]
dc.contributor.authorMÉCHIN, Françoise
hal.structure.identifierIngénierie des Matériaux Polymères [IMP]
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
dc.contributor.authorDUMON, Michel
dc.contributor.authorDURAND, Dominique
dc.contributor.authorNICOLAI, Taco
dc.date.accessioned2020
dc.date.available2020
dc.date.issued2001
dc.identifier.issn0024-9297
dc.identifier.urihttps://oskar-bordeaux.fr/handle/20.500.12278/19907
dc.description.abstractEnRandomly branched polystyrene (PS) was synthesized by end-linking monodisperse linear PS chains with divinylbenzene using controlled free radical polymerization. Samples obtained at different reaction extents were characterized using size exclusion chromatography and static and dynamic light scattering. The results are compared with those obtained on randomly branched poly(methyl methacrylate) (PMMA). The overal structure of branched PS was found to be the same as that of branched PMMA despite the very different local structure. The results strongly support the idea that the formation of polymeric gels is a universal process that may be described by the percolation model.
dc.language.isoen
dc.publisherAmerican Chemical Society
dc.title.enCharacterization of Randomly Branched Polymers Formed by End-Linking Linear Polystyrene Using Controlled Free Radical Polymerization
dc.typeArticle de revue
dc.identifier.doi10.1021/ma010113i
dc.subject.halChimie/Polymères
bordeaux.journalMacromolecules
bordeaux.page4109-4113
bordeaux.volume34
bordeaux.hal.laboratoriesLaboratoire de Chimie des Polymères Organiques (LCPO) - UMR 5629*
bordeaux.issue12
bordeaux.institutionBordeaux INP
bordeaux.institutionUniversité de Bordeaux
bordeaux.peerReviewedoui
hal.identifierhal-02045876
hal.version1
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-02045876v1
bordeaux.COinSctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Macromolecules&rft.date=2001&rft.volume=34&rft.issue=12&rft.spage=4109-4113&rft.epage=4109-4113&rft.eissn=0024-9297&rft.issn=0024-9297&rft.au=OURDOUILLIE,%20Pascal&CHAUMONT,%20Philippe&M%C3%89CHIN,%20Fran%C3%A7oise&DUMON,%20Michel&DURAND,%20Dominique&rft.genre=article


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