Selective isomerization-carbonylation of a terpene trisubstituted double bond
| dc.rights.license | open | |
| hal.structure.identifier | Univ Konstanz, Dept. Chemistry | |
| dc.contributor.author | BUSCH, Hanna | |
| hal.structure.identifier | Univ Konstanz, Dept. Chemistry | |
| dc.contributor.author | STEMPFLE, Florian | |
| hal.structure.identifier | Univ Konstanz, Dept. Chemistry | |
| dc.contributor.author | HESS, Sandra | |
| hal.structure.identifier | Laboratoire de Chimie des Polymères Organiques [LCPO] | |
| hal.structure.identifier | Team 2 LCPO : Biopolymers & Bio-sourced Polymers | |
| dc.contributor.author | GRAU, Etienne
IDREF: 187909261 | |
| hal.structure.identifier | Univ Konstanz, Dept. Chemistry | |
| dc.contributor.author | MECKING, Stefan | |
| dc.date.accessioned | 2020 | |
| dc.date.available | 2020 | |
| dc.date.issued | 2014 | |
| dc.identifier.issn | 1463-9262 | |
| dc.identifier.uri | https://oskar-bordeaux.fr/handle/20.500.12278/19785 | |
| dc.description.abstractEn | Selective catalytic carbonylation of the trisubstituted double bond of citronellic acid is enabled via an isomerization-functionalization approach. Alkoxycarbonylation with [{1,2-((Bu2PCH2)-Bu-t)(2)C6H4}Pd(OTf)(2)] as a catalyst precursor occurs with >97% selectivity for the terminal diester dimethyl-3,7-dimethylnonane-dioate. This prevails much over the typical cationic methonfaddition. The reactive primary carboxy group formed allows for e.g. the preparation of the high molecular weight novel polyester poly[3,7-dimethylnonanediyl-3,7-dimethylnonanedioate]. | |
| dc.language.iso | en | |
| dc.publisher | Royal Society of Chemistry | |
| dc.subject.en | SYSTEMS | |
| dc.subject.en | LIMONENE | |
| dc.subject.en | OLEFINS | |
| dc.subject.en | CATALYZED HYDROFORMYLATION | |
| dc.subject.en | LINEAR ALDEHYDES | |
| dc.subject.en | INTERNAL ALKENES | |
| dc.subject.en | METHYL OLEATE | |
| dc.subject.en | ACID ESTERS | |
| dc.subject.en | METHOXYCARBONYLATION | |
| dc.subject.en | MONOMERS | |
| dc.title.en | Selective isomerization-carbonylation of a terpene trisubstituted double bond | |
| dc.type | Article de revue | |
| dc.identifier.doi | 10.1039/c4gc01233j | |
| dc.subject.hal | Chimie/Polymères | |
| dc.subject.hal | Chimie/Catalyse | |
| dc.subject.hal | Chimie | |
| bordeaux.journal | Green Chemistry | |
| bordeaux.page | 4541-4545 | |
| bordeaux.volume | 16 | |
| bordeaux.hal.laboratories | Laboratoire de Chimie des Polymères Organiques (LCPO) - UMR 5629 | * |
| bordeaux.issue | 10 | |
| bordeaux.institution | Bordeaux INP | |
| bordeaux.institution | Université de Bordeaux | |
| bordeaux.peerReviewed | oui | |
| hal.identifier | hal-01366463 | |
| hal.version | 1 | |
| hal.origin.link | https://hal.archives-ouvertes.fr//hal-01366463v1 | |
| bordeaux.COinS | ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Green%20Chemistry&rft.date=2014&rft.volume=16&rft.issue=10&rft.spage=4541-4545&rft.epage=4541-4545&rft.eissn=1463-9262&rft.issn=1463-9262&rft.au=BUSCH,%20Hanna&STEMPFLE,%20Florian&HESS,%20Sandra&GRAU,%20Etienne&MECKING,%20Stefan&rft.genre=article |
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