Fatty acid-based (bis) 6-membered cyclic carbonates as efficient isocyanate free poly(hydroxyurethane) precursors
| dc.rights.license | open | |
| hal.structure.identifier | Laboratoire de Chimie des Polymères Organiques [LCPO] | |
| dc.contributor.author | MAISONNEUVE, Lise | |
| hal.structure.identifier | Laboratoire de Chimie des Polymères Organiques [LCPO] | |
| dc.contributor.author | WIROTIUS, Anne-Laure | |
| hal.structure.identifier | Institut des Corps Gras [ITERG] | |
| dc.contributor.author | ALFOS, Carine | |
| hal.structure.identifier | Laboratoire de Chimie des Polymères Organiques [LCPO] | |
| dc.contributor.author | GRAU, Etienne
IDREF: 187909261 | |
| hal.structure.identifier | Laboratoire de Chimie des Polymères Organiques [LCPO] | |
| dc.contributor.author | CRAMAIL, Henri | |
| dc.date.accessioned | 2020 | |
| dc.date.available | 2020 | |
| dc.date.issued | 2014 | |
| dc.identifier.issn | 1759-9954 | |
| dc.identifier.uri | https://oskar-bordeaux.fr/handle/20.500.12278/19781 | |
| dc.description.abstractEn | (Bis) 6-membered cyclic carbonates were prepared from methyl 10-undecenoate, which is produced from ricinoleic acid, a main constituent of castor oil. Kinetic studies on these new fatty acid-based 6-membered cyclic carbonates revealed that they are much more reactive than their homologs, 5-membered ones (30 times). Poly(hydroxyurethane)s (PHUs) were then synthesized from these bis 6-membered cyclic carbonates at a temperature as low as room temperature and in the solvent or bulk. Unexpectedly, chemical gels were obtained. The latter were the consequence of side reactions of carbonate ring-opening with the hydroxyl groups of the formed poly(hydroxyurethane)s. Quenching with a large excess of hexylamine enabled the breaking-up of the gel with the formation of urea linkages. | |
| dc.language.iso | en | |
| dc.publisher | Royal Society of Chemistry - RSC | |
| dc.subject.en | 1 3-DIOXAN-2-ONE | |
| dc.subject.en | AMINE | |
| dc.subject.en | SELECTIVITY | |
| dc.subject.en | MONOMERS | |
| dc.subject.en | REACTIVITY | |
| dc.subject.en | POLYADDITION | |
| dc.subject.en | POLYHYDROXYURETHANES | |
| dc.subject.en | POLYURETHANES | |
| dc.subject.en | MODEL REACTION | |
| dc.subject.en | DIMETHYL CARBONATE | |
| dc.title.en | Fatty acid-based (bis) 6-membered cyclic carbonates as efficient isocyanate free poly(hydroxyurethane) precursors | |
| dc.type | Article de revue | |
| dc.identifier.doi | 10.1039/c4py00922c | |
| dc.subject.hal | Chimie/Polymères | |
| bordeaux.journal | Polymer Chemistry | |
| bordeaux.page | 6142-6147 | |
| bordeaux.volume | 5 | |
| bordeaux.hal.laboratories | Laboratoire de Chimie des Polymères Organiques (LCPO) - UMR 5629 | * |
| bordeaux.issue | 21 | |
| bordeaux.institution | Bordeaux INP | |
| bordeaux.institution | Université de Bordeaux | |
| bordeaux.peerReviewed | oui | |
| hal.identifier | hal-01366250 | |
| hal.version | 1 | |
| hal.origin.link | https://hal.archives-ouvertes.fr//hal-01366250v1 | |
| bordeaux.COinS | ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Polymer%20Chemistry&rft.date=2014&rft.volume=5&rft.issue=21&rft.spage=6142-6147&rft.epage=6142-6147&rft.eissn=1759-9954&rft.issn=1759-9954&rft.au=MAISONNEUVE,%20Lise&WIROTIUS,%20Anne-Laure&ALFOS,%20Carine&GRAU,%20Etienne&CRAMAIL,%20Henri&rft.genre=article |
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