Synthesis of fatty acid-based Non-Isocyanate Polyurethanes, NIPUs, in bulk and mini-emulsion
| dc.rights.license | open | |
| hal.structure.identifier | Laboratoire de Chimie des Polymères Organiques [LCPO] | |
| dc.contributor.author | RIX, Estelle | |
| hal.structure.identifier | Laboratoire de Chimie des Polymères Organiques [LCPO] | |
| hal.structure.identifier | Team 2 LCPO : Biopolymers & Bio-sourced Polymers | |
| dc.contributor.author | GRAU, Etienne
IDREF: 187909261 | |
| hal.structure.identifier | Institut des Corps Gras [ITERG] | |
| dc.contributor.author | CHOLLET, Guillaume | |
| hal.structure.identifier | Laboratoire de Chimie des Polymères Organiques [LCPO] | |
| hal.structure.identifier | Team 2 LCPO : Biopolymers & Bio-sourced Polymers | |
| dc.contributor.author | CRAMAIL, Henri | |
| dc.date.accessioned | 2020 | |
| dc.date.available | 2020 | |
| dc.date.issued | 2016 | |
| dc.identifier.issn | 0014-3057 | |
| dc.identifier.uri | https://oskar-bordeaux.fr/handle/20.500.12278/19771 | |
| dc.description.abstractEn | The synthesis of fatty acid-based poly(hydroxy urethane)s, PHUs, was investigated. Bulk polymerization of fatty acid-based bis-carbonates with fatty acid diamine, Priamine® 1075, was first studied, allowing us to prepare non-isocyanate polyurethanes, NIPUs, at low temperature (60 °C) and in few hours. Water-borne NIPUs latexes were then prepared with the same monomers through mini-emulsion process. Different surfactants and hydrophobic additives were tested in order to obtain stable emulsions and polymer particles. NIPUs latexes with solid content up to 30 wt.% could be achieved. As a general trend, NIPUs prepared in mini-emulsion exhibited lower molar masses than the ones formed in bulk, phenomenon explained by the partial hydrolysis of cyclic carbonates. | |
| dc.language.iso | en | |
| dc.publisher | Elsevier | |
| dc.subject.en | Poly(hydroxy urethane) | |
| dc.subject.en | NIPUs | |
| dc.subject.en | mini-emulsion | |
| dc.subject.en | latex | |
| dc.subject.en | fatty acids | |
| dc.subject.en | water-borne | |
| dc.title.en | Synthesis of fatty acid-based Non-Isocyanate Polyurethanes, NIPUs, in bulk and mini-emulsion | |
| dc.type | Article de revue | |
| dc.identifier.doi | 10.1016/j.eurpolymj.2016.07.006 | |
| dc.subject.hal | Chimie/Polymères | |
| dc.subject.hal | Chimie/Matériaux | |
| dc.subject.hal | Chimie | |
| bordeaux.journal | European Polymer Journal | |
| bordeaux.page | 863-872 | |
| bordeaux.volume | 84 | |
| bordeaux.hal.laboratories | Laboratoire de Chimie des Polymères Organiques (LCPO) - UMR 5629 | * |
| bordeaux.institution | Bordeaux INP | |
| bordeaux.institution | Université de Bordeaux | |
| bordeaux.peerReviewed | oui | |
| hal.identifier | hal-01373137 | |
| hal.version | 1 | |
| hal.origin.link | https://hal.archives-ouvertes.fr//hal-01373137v1 | |
| bordeaux.COinS | ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=European%20Polymer%20Journal&rft.date=2016&rft.volume=84&rft.spage=863-872&rft.epage=863-872&rft.eissn=0014-3057&rft.issn=0014-3057&rft.au=RIX,%20Estelle&GRAU,%20Etienne&CHOLLET,%20Guillaume&CRAMAIL,%20Henri&rft.genre=article |
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