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ADMET polymerization of bio-based biphenyl compounds

dc.rights.licenseopen
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
dc.contributor.authorLLEVOT, Audrey
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
hal.structure.identifierTeam 2 LCPO : Biopolymers & Bio-sourced Polymers
dc.contributor.authorGRAU, Etienne
IDREF: 187909261
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
hal.structure.identifierTeam 1 LCPO : Polymerization Catalyses & Engineering
dc.contributor.authorCARLOTTI, Stéphane
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
hal.structure.identifierTeam 2 LCPO : Biopolymers & Bio-sourced Polymers
dc.contributor.authorGRELIER, Stéphane
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
hal.structure.identifierTeam 2 LCPO : Biopolymers & Bio-sourced Polymers
dc.contributor.authorCRAMAIL, Henri
dc.date.accessioned2020
dc.date.available2020
dc.date.issued2015
dc.identifier.issn1759-9954
dc.identifier.urihttps://oskar-bordeaux.fr/handle/20.500.12278/19765
dc.description.abstractEnFour biphenyl monomers derived from vanillin or eugenol were synthesized and polymerized by the ADMET methodology. The biphenyl compounds were produced by enzymatic dimerization of 2-methoxy-4-methylphenol, methyl vanillate, vanillin and eugenol. Further chemical modifications of the obtained dimers such as transesterification, Wittig reaction or allylation led to a,.-dienes. The reactivity of these bio-based monomers towards ADMET polymerization employing several catalysts was investigated. Only oligomers were obtained when the diallylated compound was employed. The polymers based on dieugenol and the bis-unsaturated diester exhibit good thermal stability and T-g at 17 and 54 degrees C, respectively. Polymerization of the divinyl compound obtained by the Wittig reaction of divanillin showed a reasonable molar mass of 30 000 g mol(-1), a high T-g at around 160 degrees C and thermostability with a 5% weight loss occurring at 380 degrees C.
dc.language.isoen
dc.publisherRoyal Society of Chemistry - RSC
dc.title.enADMET polymerization of bio-based biphenyl compounds
dc.typeArticle de revue
dc.identifier.doi10.1039/c5py01232e
dc.subject.halChimie/Polymères
dc.subject.halChimie/Matériaux
dc.subject.halChimie
bordeaux.journalPolymer Chemistry
bordeaux.page7693-7700
bordeaux.volume6
bordeaux.hal.laboratoriesLaboratoire de Chimie des Polymères Organiques (LCPO) - UMR 5629*
bordeaux.issue44
bordeaux.institutionBordeaux INP
bordeaux.institutionUniversité de Bordeaux
bordeaux.peerReviewedoui
hal.identifierhal-01366055
hal.version1
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-01366055v1
bordeaux.COinSctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Polymer%20Chemistry&rft.date=2015&rft.volume=6&rft.issue=44&rft.spage=7693-7700&rft.epage=7693-7700&rft.eissn=1759-9954&rft.issn=1759-9954&rft.au=LLEVOT,%20Audrey&GRAU,%20Etienne&CARLOTTI,%20St%C3%A9phane&GRELIER,%20St%C3%A9phane&CRAMAIL,%20Henri&rft.genre=article


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