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Polynorbornene latex synthesis by UV-triggered Ring-Opening Metathesis Polymerization in miniemulsion
dc.rights.license | open | |
hal.structure.identifier | Laboratoire de Chimie des Polymères Organiques [LCPO] | |
hal.structure.identifier | Team 1 LCPO : Polymerization Catalyses & Engineering | |
dc.contributor.author | PICHAVANT, Loïc | |
hal.structure.identifier | Institut Charles Gerhardt Montpellier - Institut de Chimie Moléculaire et des Matériaux de Montpellier [ICGM ICMMM] | |
dc.contributor.author | LACROIX-DESMAZES, Patrick | |
hal.structure.identifier | Departement de Photochimie Générale | |
hal.structure.identifier | Institut de Science des Matériaux de Mulhouse [IS2M] | |
dc.contributor.author | CHEMTOB, Abraham | |
hal.structure.identifier | Institut Charles Gerhardt Montpellier - Institut de Chimie Moléculaire et des Matériaux de Montpellier [ICGM ICMMM] | |
dc.contributor.author | PINAUD, Julien | |
hal.structure.identifier | Laboratoire de Chimie des Polymères Organiques [LCPO] | |
hal.structure.identifier | Team 1 LCPO : Polymerization Catalyses & Engineering | |
dc.contributor.author | HÉROGUEZ, Valérie | |
dc.date.accessioned | 2020 | |
dc.date.available | 2020 | |
dc.date.issued | 2020 | |
dc.identifier.issn | 0032-3861 | |
dc.identifier.uri | https://oskar-bordeaux.fr/handle/20.500.12278/19729 | |
dc.description.abstractEn | An innovative route based on a novel photo-latent ROMP initiator has been explored to synthesize polynorbornene latex particles in miniemulsion. Operation conditions were strongly improved by the use of an annular LED photo-reactor, increasing the uniformity of radiation distribution and enabling to control atmosphere and stirring throughout irradiation. Several parameters (droplet size, irradiance, pre-catalyst structure) were studied in order to improve the monomer conversion profiles, which eventually led to the production of latex with high norbornene conversion (>90%) and 10% solids content. Particular attention was paid to the polymer microstructure, which was found to be highly dependent on the type of initiation mechanism. | |
dc.language.iso | en | |
dc.publisher | Elsevier | |
dc.subject.en | Ring-Opening Metathesis Polymerization | |
dc.subject.en | polymerization in miniemulsion | |
dc.subject.en | latex | |
dc.subject.en | Photo-latent initiator | |
dc.title.en | Polynorbornene latex synthesis by UV-triggered Ring-Opening Metathesis Polymerization in miniemulsion | |
dc.type | Article de revue | |
dc.identifier.doi | 10.1016/j.polymer.2020.122200 | |
dc.subject.hal | Chimie/Polymères | |
bordeaux.journal | Polymer | |
bordeaux.page | 122200 | |
bordeaux.volume | 190 | |
bordeaux.hal.laboratories | Laboratoire de Chimie des Polymères Organiques (LCPO) - UMR 5629 | * |
bordeaux.institution | Bordeaux INP | |
bordeaux.institution | Université de Bordeaux | |
bordeaux.peerReviewed | oui | |
hal.identifier | hal-02467679 | |
hal.version | 1 | |
hal.origin.link | https://hal.archives-ouvertes.fr//hal-02467679v1 | |
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