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Core-Shell Double Gyroid Structure Formed by Linear ABC Terpolymer Thin Films

dc.rights.licenseopen
hal.structure.identifierTeam 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
dc.contributor.authorANTOINE, Ségolène
hal.structure.identifierTeam 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
dc.contributor.authorAISSOU, Karim
hal.structure.identifierTeam 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
dc.contributor.authorMUMTAZ, Muhammad
hal.structure.identifierTeam 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
dc.contributor.authorTELITEL, Siham
hal.structure.identifierTeam 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
dc.contributor.authorPECASTAINGS, Gilles
hal.structure.identifierTeam 1 LCPO : Polymerization Catalyses & Engineering
dc.contributor.authorWIROTIUS, Anne-Laure
hal.structure.identifierTeam 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
dc.contributor.authorBROCHON, Cyril
hal.structure.identifierTeam 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
dc.contributor.authorCLOUTET, Eric
IDREF: 151048681
hal.structure.identifierTeam 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
dc.contributor.authorFLEURY, Guillaume
hal.structure.identifierTeam 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
dc.contributor.authorHADZIIOANNOU, Georges
dc.date.accessioned2020
dc.date.available2020
dc.date.issued2018
dc.identifier.issn1022-1336
dc.identifier.urihttps://oskar-bordeaux.fr/handle/20.500.12278/19644
dc.description.abstractEnThe synthesis and self-assembly in thin-film configuration of linear ABC triblock terpolymer chains consisting of polystyrene (PS), poly(2-vinylpyridine) (P2VP), and polyisoprene (PI) are described. For that purpose, a hydroxylterminated PS-b-P2VP (45 kg mol−1) building block and a carboxyl-terminated PI (9 kg mol−1) are first separately prepared by anionic polymerization, and then are coupled via a Steglich esterification reaction. This quantitative and metal-free catalyst synthesis route reveals to be very interesting since functionalization and purification steps are straightforward, and well-defined terpolymers are produced. A solvent vapor annealing (SVA) process is used to promote the self-assembly of frustrated PS-b-P2VP-b-PI chains into a thinfilm core–shell double gyroid (Q230, space group: Ia3d) structure. As terraces are formed within PS-b-P2VP-b-PI thin films during the SVA process under a CHCl3 vapor, different plane orientations of the Q230 structure ((211), (110), (111), and (100)) are observed at the polymer–air interface depending on the film thickness.
dc.language.isoen
dc.publisherWiley-VCH Verlag
dc.subject.enself-assembly
dc.subject.enanionic polymerization
dc.subject.encore–shell double gyroid structure
dc.subject.enselfassembly
dc.subject.enSteglich esterification
dc.subject.enthin films
dc.subject.enCore-shell double gyroid structure
dc.subject.enthin film
dc.title.enCore-Shell Double Gyroid Structure Formed by Linear ABC Terpolymer Thin Films
dc.typeArticle de revue
dc.identifier.doi10.1002/marc.201800043
dc.subject.halChimie/Polymères
bordeaux.journalMacromolecular Rapid Communications
bordeaux.page1800043
bordeaux.volume39
bordeaux.hal.laboratoriesLaboratoire de Chimie des Polymères Organiques (LCPO) - UMR 5629*
bordeaux.issue9
bordeaux.institutionBordeaux INP
bordeaux.institutionUniversité de Bordeaux
bordeaux.peerReviewedoui
hal.identifierhal-01755261
hal.version1
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-01755261v1
bordeaux.COinSctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Macromolecular%20Rapid%20Communications&rft.date=2018&rft.volume=39&rft.issue=9&rft.spage=1800043&rft.epage=1800043&rft.eissn=1022-1336&rft.issn=1022-1336&rft.au=ANTOINE,%20S%C3%A9gol%C3%A8ne&AISSOU,%20Karim&MUMTAZ,%20Muhammad&TELITEL,%20Siham&PECASTAINGS,%20Gilles&rft.genre=article


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