Low-temperature amino-based catalyst activation for on-demand polyurethane synthesis
dc.rights.license | open | |
hal.structure.identifier | Laboratoire de Chimie des Polymères Organiques [LCPO] | |
hal.structure.identifier | Team 1 LCPO : Polymerization Catalyses & Engineering | |
dc.contributor.author | LAMBERT, Romain | |
hal.structure.identifier | Laboratoire de Chimie des Polymères Organiques [LCPO] | |
dc.contributor.author | IBARBOURE, Emmanuel | |
hal.structure.identifier | Laboratoire de Chimie des Polymères Organiques [LCPO] | |
hal.structure.identifier | Team 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies | |
dc.contributor.author | FLEURY, Guillaume | |
hal.structure.identifier | Laboratoire de Chimie des Polymères Organiques [LCPO] | |
hal.structure.identifier | Team 1 LCPO : Polymerization Catalyses & Engineering | |
dc.contributor.author | CARLOTTI, Stéphane | |
dc.date.accessioned | 2020 | |
dc.date.available | 2020 | |
dc.date.issued | 2020 | |
dc.identifier.issn | 0032-3896 | |
dc.identifier.uri | https://oskar-bordeaux.fr/handle/20.500.12278/19641 | |
dc.description.abstractEn | A new latent catalyst, based on 1,5-diazabicyclo[4.3.0]non-5-ene (DBN), has been specifically designed to be thermally deprotected at low temperature. More generally, specific isocyanurates based on the reaction of two substituted isocyanates and DBN are used as pre-catalyst for polyurethane synthesis. The activation temperature of the pre-catalysts is determined by DSC and resulting free catalysts activity is demonstrated through a catalysis cycle on a PU model reaction. | |
dc.language.iso | en | |
dc.publisher | Nature Publishing Group | |
dc.subject.en | organic catalyst | |
dc.subject.en | Polyurethane | |
dc.subject.en | latent catalyst | |
dc.subject.en | activation | |
dc.title.en | Low-temperature amino-based catalyst activation for on-demand polyurethane synthesis | |
dc.type | Article de revue | |
dc.identifier.doi | 10.1038/s41428-019-0246-8 | |
dc.subject.hal | Chimie/Polymères | |
bordeaux.journal | Polymer Journal | |
bordeaux.page | 45-49 | |
bordeaux.volume | 52 | |
bordeaux.hal.laboratories | Laboratoire de Chimie des Polymères Organiques (LCPO) - UMR 5629 | * |
bordeaux.issue | 1 | |
bordeaux.institution | Bordeaux INP | |
bordeaux.institution | Université de Bordeaux | |
bordeaux.peerReviewed | oui | |
hal.identifier | hal-02431122 | |
hal.version | 1 | |
hal.origin.link | https://hal.archives-ouvertes.fr//hal-02431122v1 | |
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