Synthesis of Carboxyl-EDOT as a Versatile Addition and Additive to PEDOT:PSS
| dc.rights.license | open | |
| hal.structure.identifier | Laboratoire de Chimie des Polymères Organiques [LCPO] | |
| dc.contributor.author | MANTIONE, Daniele | |
| hal.structure.identifier | Laboratoire de Chimie des Polymères Organiques [LCPO] | |
| dc.contributor.author | MARQUEZ, Ariana Villarroel | |
| hal.structure.identifier | Laboratoire de Chimie des Polymères Organiques [LCPO] | |
| dc.contributor.author | CRUCIANI, Federico | |
| hal.structure.identifier | Laboratoire de Chimie des Polymères Organiques [LCPO] | |
| dc.contributor.author | BROCHON, Cyril | |
| hal.structure.identifier | Laboratoire de Chimie des Polymères Organiques [LCPO] | |
| dc.contributor.author | CLOUTET, Eric
IDREF: 151048681 | |
| hal.structure.identifier | Laboratoire de Chimie des Polymères Organiques [LCPO] | |
| dc.contributor.author | HADZIIOANNOU, Georges | |
| dc.date.accessioned | 2020 | |
| dc.date.available | 2020 | |
| dc.date.issued | 2019 | |
| dc.identifier.issn | 2161-1653 | |
| dc.identifier.uri | https://oskar-bordeaux.fr/handle/20.500.12278/19637 | |
| dc.description.abstractEn | Two steps synthesis of EDOT (3,4-ethylenedioxythiophene) derivate bearing a carboxylic acid group (carboxyl-EDOT) is presented. This reactive monomer has been copolymerized with EDOT to afford PEDOT copolymers. Thanks to the most common additives usually added to the PEDOT:PSS dispersion, ethylene glycol and 4-Dodecylbenzenesulfonic acid (DBSA), the carboxylic acid has been used to crosslink the material via esterification reactions. This result offers the possibility to produce a polymer network without adding any crosslinking agent. Furthermore, the short synthetic pathway of carboxyl-EDOT offers the possibility to incorporate new functionality either in EDOT monomer or in PEDOT materials with a reasonable chemical effort and background. | |
| dc.language.iso | en | |
| dc.publisher | Washington, D.C : American Chemical Society | |
| dc.subject.en | carboxyl-EDOT | |
| dc.subject.en | PEDOT | |
| dc.subject.en | cross-link | |
| dc.subject.en | conducting polymers | |
| dc.subject.en | electronic material | |
| dc.title.en | Synthesis of Carboxyl-EDOT as a Versatile Addition and Additive to PEDOT:PSS | |
| dc.type | Article de revue | |
| dc.identifier.doi | 10.1021/acsmacrolett.8b00970 | |
| dc.subject.hal | Chimie/Polymères | |
| bordeaux.journal | ACS Macro Letters | |
| bordeaux.page | 285-288 | |
| bordeaux.volume | 8 | |
| bordeaux.hal.laboratories | Laboratoire de Chimie des Polymères Organiques (LCPO) - UMR 5629 | * |
| bordeaux.issue | 3 | |
| bordeaux.institution | Bordeaux INP | |
| bordeaux.institution | Université de Bordeaux | |
| bordeaux.peerReviewed | oui | |
| hal.identifier | hal-02107646 | |
| hal.version | 1 | |
| hal.origin.link | https://hal.archives-ouvertes.fr//hal-02107646v1 | |
| bordeaux.COinS | ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=ACS%20Macro%20Letters&rft.date=2019&rft.volume=8&rft.issue=3&rft.spage=285-288&rft.epage=285-288&rft.eissn=2161-1653&rft.issn=2161-1653&rft.au=MANTIONE,%20Daniele&MARQUEZ,%20Ariana%20Villarroel&CRUCIANI,%20Federico&BROCHON,%20Cyril&CLOUTET,%20Eric&rft.genre=article |
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