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An Alternative Anionic Polyelectrolyte for Aqueous PEDOT Dispersions: Towards Printable Transparent Electrodes

dc.rights.licenseopen
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
hal.structure.identifierTeam 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
dc.contributor.authorHOFMANN, Anna
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
hal.structure.identifierTeam 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
dc.contributor.authorSMAAL, Wiljan
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
hal.structure.identifierTeam 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
dc.contributor.authorMUMTAZ, Muhammad
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
hal.structure.identifierTeam 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
dc.contributor.authorKATSIGIANNOPOULOS, Dimitrios
hal.structure.identifierTeam 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
dc.contributor.authorBROCHON, Cyril
hal.structure.identifierFraunhofer Institute for Organic Electronics, Electron Beam and Plasma Technology [Fraunhofer FEP]
dc.contributor.authorSCHÜTZE, Falk
hal.structure.identifierFraunhofer Institute for Organic Electronics, Electron Beam and Plasma Technology [Fraunhofer FEP]
dc.contributor.authorHILD, Olaf
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
hal.structure.identifierTeam 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
dc.contributor.authorCLOUTET, Eric
IDREF: 151048681
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
hal.structure.identifierTeam 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
dc.contributor.authorHADZIIOANNOU, Georges
dc.date.accessioned2020
dc.date.available2020
dc.date.issued2015
dc.identifier.issn1433-7851
dc.identifier.urihttps://oskar-bordeaux.fr/handle/20.500.12278/19618
dc.description.abstractEnOrganic conducting polymers are promising electrode materials for printable organic electronics. One of the most studied conducting polymers is PEDOT:PSS which is sufficiently conductive and transparent, but which shows some drawbacks, such as hygroscopy and acidity. In this communication we present a new approach to stabilize PEDOT in aqueous dispersions by replacing the PSS with a new basic polyanion based on a polystyrene backbone with (trifluoromethylsulfonyl)imide (TSFI) side groups. The PEDOT:PSTFSIK dispersions were obtained by oxidative polymerization of EDOT in aqueous PSTFSIK solution and were characterized regarding their composition, morphology, doping, rheological behavior and opto-electronic performance. These PEDOT:PSTFSIK dispersions show excellent printability and good opto-electronic performance (238Ohm.sq-1 at 91% transmittance, >260S.cm-1) and were successfully integrated as flexible electrodes in OLED and OPV devices.
dc.language.isoen
dc.publisherWiley-VCH Verlag
dc.subject.enPEDOT
dc.subject.enconducting polymers
dc.subject.endispersion
dc.subject.enprinted organic electronics
dc.subject.entransparent electrode
dc.subject.enflexible OLED
dc.subject.enflexible OPV
dc.title.enAn Alternative Anionic Polyelectrolyte for Aqueous PEDOT Dispersions: Towards Printable Transparent Electrodes
dc.typeArticle de revue
dc.identifier.doi10.1002/anie.201503024
dc.subject.halChimie/Polymères
bordeaux.journalAngewandte Chemie International Edition
bordeaux.page8506-8510
bordeaux.volume54
bordeaux.hal.laboratoriesLaboratoire de Chimie des Polymères Organiques (LCPO) - UMR 5629*
bordeaux.issue29
bordeaux.institutionBordeaux INP
bordeaux.institutionUniversité de Bordeaux
bordeaux.peerReviewedoui
hal.identifierhal-02922667
hal.version1
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-02922667v1
bordeaux.COinSctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Angewandte%20Chemie%20International%20Edition&rft.date=2015&rft.volume=54&rft.issue=29&rft.spage=8506-8510&rft.epage=8506-8510&rft.eissn=1433-7851&rft.issn=1433-7851&rft.au=HOFMANN,%20Anna&SMAAL,%20Wiljan&MUMTAZ,%20Muhammad&KATSIGIANNOPOULOS,%20Dimitrios&BROCHON,%20Cyril&rft.genre=article


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